红海作为腐蚀性环境:7075、2024和6061铝合金的腐蚀速率和腐蚀机制

IF 1.5 Q4 ELECTROCHEMISTRY
A. Al-Moubaraki, Hind H. Al-Rushud
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引用次数: 18

摘要

采用失重(WL)测量和动电位极化(PDP)技术研究了Al 7075、Al 2024和Al 6061在红海海水中的腐蚀行为。利用光学摄影(OP)、扫描电子显微镜(SEM)和能谱分析(EDS)对铝合金的腐蚀模式和腐蚀产物进行了表征。结果表明,WL数据符合双峰模型而非幂律函数,腐蚀速率随暴露时间的增加而持续降低。所研究的铝合金红海腐蚀性能的增大顺序为:Al 6061 < Al 2024 < Al 7075。温度效应结果表明,温度升高导致阳极和阴极电流密度增加,腐蚀电位降低。Al 7075受温度的影响较小。在红海中长时间浸泡后,所有铝合金表面的腐蚀模式以点蚀为主。腐蚀后的Al 7075能谱出现S峰,说明细菌在腐蚀过程中的作用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The Red Sea as a Corrosive Environment: Corrosion Rates and Corrosion Mechanism of Aluminum Alloys 7075, 2024, and 6061
Corrosion behavior of Al 7075, Al 2024, and Al 6061 in the Red Sea water was studied using weight loss (WL) measurements and potentiodynamic polarization (PDP) technique. The corrosion patterns and corrosion products formed on Al alloys were characterized using optical photography (OP), scanning electron microscopy (SEM), and energy-dispersive spectroscopy (EDS). The results showed that WL data were consistent with bimodal model rather than the power law function and the corrosion rates exhibit a continuous decrease with exposure time. The increasing order of the Red Sea corrosivity on the studied Al alloys can be given as follows: Al 6061 < Al 2024 < Al 7075. The results of temperature effect revealed that an increase in temperature resulted in an increase in both anodic and cathodic current density and a decrease in corrosion potential. Al 7075 was less influenced by temperature than the other alloys. Pitting corrosion was the predominant corrosion pattern detected on all Al alloy surfaces after prolonged immersion in the Red Sea water. The appearance of S peak in EDS spectra of Al 7075 after corrosion gives an indication of the contribution of bacteria in the corrosion process.
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来源期刊
CiteScore
5.70
自引率
0.00%
发文量
8
审稿时长
14 weeks
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