杂化纳米粒子增强不饱和聚酯树脂的制备及力学性能研究

S. Salih, W. B. Salih, H. Hamad
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引用次数: 1

摘要

本研究以不饱和聚酯树脂(UP)为原料,制备了纳米复合高分子材料。采用手工叠层法制备了两组纳米复合材料。第一组由颗粒尺寸为83.98nm的氧化锆和氧化钇(30mol%Y2O3-ZrO2)的混合物纳米颗粒增强的(UP)组成对复合材料的性能进行了研究。结果表明,两组纳米复合材料的弯曲模量、冲击强度和断裂韧度值都随着纳米颗粒体积分数比的增加而增加,而弯曲强度值也随着纳米颗粒容积分数比的增大而降低。此外,与仅由锆纳米粒子增强的复合材料相比,由杂化纳米粒子增强的不饱和聚酯树脂具有更高的机械性能。断裂表面的形态形成显示出所制备的聚合物组合物的所有组分之间的紧密互连。这增强了不饱和聚酯树脂和增强纳米颗粒之间的良好兼容性,从而增强了机械性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
PREPARATION AND INVESTIGATION OF SOME MECHANICAL PROPERTIES OF UNSATURATED POLYESTER RESIN REINFORCED BY HYBRID NANOPARTICLES
In this study, nano-composite of polymeric materials, prepared from unsaturated polyesterresin (UP). Two groups of nanocomposites were prepared by Hand Lay-up method. The firstgroup consists from (UP) reinforced by hybrid nanoparticles consisting of a mixture ofzirconium oxide and yttrium oxide (30 mol%Y2O3- ZrO2) with particles size (83.98nm). Thesecond group consists of (UP) reinforced by zirconia nanoparticles (ZrO2) with particle size(47.23nm). The effect of volume fraction (0.5%, 1%, 1.5%, 2%, 2.5%, 3%) of thenanoparticles additives on some mechanical properties of composites materials was studiedalso. The results shown that the values of the flexural modulus, impact strength and fracturetoughness increased, as the volume fraction ratio of the nanoparticle increased for bothgroups of nanocomposites, while flexural strength values decreased with the increased thevolume fraction ratio of the nanoparticles for both groups of nanocomposites also. As wellas, the unsaturated polyester resins reinforced by hybrid nanoparticles has higher mechanicalproperties as compared with their counterparts of composites reinforced by zirconiananoparticles only. The morphological formation of the fracture surface showed a closeinterconnection between all components of the prepared polymeric compositions. Thisreinforce a good compatibility between unsaturated polyester resins and reinforcementnanoparticles, which enhancement the mechanical properties.
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