铝铁配合物与EBr3复合生成的二溴金属铁配合物(E = Al, Ga)
IF 1.1
4区 化学
Q3 CHEMISTRY, MULTIDISCIPLINARY
引用次数: 14
摘要
以铝原子上带有大取代基的单溴铝多铁配合物与AlBr3反应合成了首个二溴铝多铁配合物[Br2Al-FeCp (CO)2]，并通过x射线晶体学分析和核磁共振测量对其结构进行了表征。单溴铝多铁配合物与GaBr3的反应表明，这些反应是通过取代基的相互重组进行的。本文章由计算机程序翻译，如有差异，请以英文原文为准。
Dibromometallyl-iron complexes generated by the recombination of an alumanyl-iron complex with EBr3 (E = Al, Ga)
The first dibromoalumanyl-iron complex [Br2Al–FeCp(CO)2] was synthesized by the reaction of monobromoalumanyl-iron complex bearing a bulky substituent on aluminum atom with AlBr3, whose structure was determined by the X-ray crystallographic analysis and the NMR measurement. The reactions monobromoalumanyl-iron complex with GaBr3 show that these reactions would proceed by the mutual recombination of substituents.
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来源期刊
Heteroatom Chemistry
化学-化学综合
CiteScore
1.20
自引率
0.00%
发文量
5
审稿时长
6 months
期刊介绍：
Heteroatom Chemistry brings together a broad, interdisciplinary group of chemists who work with compounds containing main-group elements of groups 13 through 17 of the Periodic Table, and certain other related elements. The fundamental reactivity under investigation should, in all cases, be concentrated about the heteroatoms. It does not matter whether the compounds being studied are acyclic or cyclic; saturated or unsaturated; monomeric, polymeric or solid state in nature; inorganic, organic, or naturally occurring, so long as the heteroatom is playing an essential role. Computational, experimental, and combined studies are equally welcome.
Subject areas include (but are by no means limited to):
-Reactivity about heteroatoms for accessing new products or synthetic pathways
-Unusual valency main-group element compounds and their properties
-Highly strained (e.g. bridged) main-group element compounds and their properties
-Photochemical or thermal cleavage of heteroatom bonds and the resulting reactivity
-Uncommon and structurally interesting heteroatom-containing species (including those containing multiple bonds and catenation)
-Stereochemistry of compounds due to the presence of heteroatoms
-Neighboring group effects of heteroatoms on the properties of compounds
-Main-group element compounds as analogues of transition metal compounds
-Variations and new results from established and named reactions (including Wittig, Kabachnik–Fields, Pudovik, Arbuzov, Hirao, and Mitsunobu)
-Catalysis and green syntheses enabled by heteroatoms and their chemistry
-Applications of compounds where the heteroatom plays a critical role.
In addition to original research articles on heteroatom chemistry, the journal welcomes focused review articles that examine the state of the art, identify emerging trends, and suggest future directions for developing fields.
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