O. Balaban, O. Izhyk, A. Zaichenk, N. Mitina, I. Grygorchak, K. Harhay
{"title":"非晶和结晶二硫化钼中Li+嵌入电流的产生:实验与理论","authors":"O. Balaban, O. Izhyk, A. Zaichenk, N. Mitina, I. Grygorchak, K. Harhay","doi":"10.3952/physics.2023.63.1.4","DOIUrl":null,"url":null,"abstract":"In this work, crystalline and amorphous nano-MoS2 materials for effective Li+-intercalation current generation have been synthesized. The effect of disordering on the structural and electrochemical properties of nano-MoS2 has been systematically investigated by multiple characterizations: transmission electron microscopy (TEM), X-ray diffraction method and electrochemical measurements. Thermodynamic and kinetic peculiarities of intercalation processes have been studied. Dependences of the change in Gibbs’ free energy of the intercalation reaction on the extent of ‘guest’ lithium loading are analyzed. The distinctive feature of disordered structures is their ability to show colossal lithium ‘guest’ load, which ensures the specific capacity of the material in cathode processes up to ~2500 mAh·g–1 under the discharge not less than 2.6 V relative to lithium. The diffusion coefficient of lithium cations in the structure of disordered nano-MoS2 is two orders of magnitude higher than that in the crystalline MoS2.A quantum-mechanical model of the observed phenomena is suggested.","PeriodicalId":18144,"journal":{"name":"Lithuanian Journal of Physics","volume":" ","pages":""},"PeriodicalIF":0.3000,"publicationDate":"2023-04-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Li+ intercalation current generation in amorphous and crystalline MoS2: Experiment and theory\",\"authors\":\"O. Balaban, O. Izhyk, A. Zaichenk, N. Mitina, I. Grygorchak, K. Harhay\",\"doi\":\"10.3952/physics.2023.63.1.4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this work, crystalline and amorphous nano-MoS2 materials for effective Li+-intercalation current generation have been synthesized. The effect of disordering on the structural and electrochemical properties of nano-MoS2 has been systematically investigated by multiple characterizations: transmission electron microscopy (TEM), X-ray diffraction method and electrochemical measurements. Thermodynamic and kinetic peculiarities of intercalation processes have been studied. Dependences of the change in Gibbs’ free energy of the intercalation reaction on the extent of ‘guest’ lithium loading are analyzed. The distinctive feature of disordered structures is their ability to show colossal lithium ‘guest’ load, which ensures the specific capacity of the material in cathode processes up to ~2500 mAh·g–1 under the discharge not less than 2.6 V relative to lithium. The diffusion coefficient of lithium cations in the structure of disordered nano-MoS2 is two orders of magnitude higher than that in the crystalline MoS2.A quantum-mechanical model of the observed phenomena is suggested.\",\"PeriodicalId\":18144,\"journal\":{\"name\":\"Lithuanian Journal of Physics\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":0.3000,\"publicationDate\":\"2023-04-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Lithuanian Journal of Physics\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://doi.org/10.3952/physics.2023.63.1.4\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"PHYSICS, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Lithuanian Journal of Physics","FirstCategoryId":"101","ListUrlMain":"https://doi.org/10.3952/physics.2023.63.1.4","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, MULTIDISCIPLINARY","Score":null,"Total":0}
Li+ intercalation current generation in amorphous and crystalline MoS2: Experiment and theory
In this work, crystalline and amorphous nano-MoS2 materials for effective Li+-intercalation current generation have been synthesized. The effect of disordering on the structural and electrochemical properties of nano-MoS2 has been systematically investigated by multiple characterizations: transmission electron microscopy (TEM), X-ray diffraction method and electrochemical measurements. Thermodynamic and kinetic peculiarities of intercalation processes have been studied. Dependences of the change in Gibbs’ free energy of the intercalation reaction on the extent of ‘guest’ lithium loading are analyzed. The distinctive feature of disordered structures is their ability to show colossal lithium ‘guest’ load, which ensures the specific capacity of the material in cathode processes up to ~2500 mAh·g–1 under the discharge not less than 2.6 V relative to lithium. The diffusion coefficient of lithium cations in the structure of disordered nano-MoS2 is two orders of magnitude higher than that in the crystalline MoS2.A quantum-mechanical model of the observed phenomena is suggested.
期刊介绍:
The main aim of the Lithuanian Journal of Physics is to reflect the most recent advances in various fields of theoretical, experimental, and applied physics, including: mathematical and computational physics; subatomic physics; atoms and molecules; chemical physics; electrodynamics and wave processes; nonlinear and coherent optics; spectroscopy.