Nagarjuna Boppana, Robyn A. Snow, Paul S. Simone, G. L. Emmert, Michael A. Brown
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Automated system for performing pH-based titrations
Abstract Liquid delivery and endpoint determination during titrations may be problematic if an analyst does not have adequate training or formal education. This can lead to issues with method accuracy and precision. This work is focused on the development of a simple, low-cost, automated system capable of performing potentiometric titrations with a push of a button. A single-board computer (Raspberry Pi), a stepper motor-based syringe pump, and a commercially available pH sensor circuit board were the primary components used to construct the auto-titrator system. Open-source Python programming language was used to control and coordinate components and provide a simple-to-use graphical user interface. A standard alkalinity method for drinking and raw water was evaluated and yielded an accuracy (recovery) between 92% and 104% for concentrations above 10 mg L−1. The precision of the method was less than 5% regardless of concentration. The developed titrator was tested at Lebanon, TN, and Woodruff, SC water treatment plants. The system was also certified by LabtronX to perform alkalinity measurements in Lebanon, TN, and served the plant operators for the past two years.
期刊介绍:
Instrumentation Science & Technology is an internationally acclaimed forum for fast publication of critical, peer reviewed manuscripts dealing with innovative instrument design and applications in chemistry, physics biotechnology and environmental science. Particular attention is given to state-of-the-art developments and their rapid communication to the scientific community.
Emphasis is on modern instrumental concepts, though not exclusively, including detectors, sensors, data acquisition and processing, instrument control, chromatography, electrochemistry, spectroscopy of all types, electrophoresis, radiometry, relaxation methods, thermal analysis, physical property measurements, surface physics, membrane technology, microcomputer design, chip-based processes, and more.
Readership includes everyone who uses instrumental techniques to conduct their research and development. They are chemists (organic, inorganic, physical, analytical, nuclear, quality control) biochemists, biotechnologists, engineers, and physicists in all of the instrumental disciplines mentioned above, in both the laboratory and chemical production environments. The journal is an important resource of instrument design and applications data.