T. Romero, L. Melo, María Esparragoza, Rosarmy Ávila, A. Moronta, G. Carruyo, L. García, C. Donoso, Laura Sáenz, Carlos Yugcha-Pilamunga
{"title":"双金属Pd-Pt/HY催化剂的甲苯加氢和开环反应","authors":"T. Romero, L. Melo, María Esparragoza, Rosarmy Ávila, A. Moronta, G. Carruyo, L. García, C. Donoso, Laura Sáenz, Carlos Yugcha-Pilamunga","doi":"10.18273/revuin.v22n1-2023003","DOIUrl":null,"url":null,"abstract":"Bimetallic Pd-Pt/HY catalysts prepared by the co-impregnation method with an atomic variation of Pd/Pd+Pt were studied to convert toluene and methylcyclohexane. The catalysts were characterized by the BET method, chemisorption of CO by the pulse method, programmed temperature reduction (H2-TPR), and programmed ammonia thermo-desorption (NH3TPD). Results of chemisorption of CO and H2-TPR for Pd-Pt/HY catalysts suggest the existence of a strong interaction between Pd and Pt. The NH3-TPD showed that incorporating metals influences the percentage of relative distribution of weak/strong acid sites presented in decreasing order of acidity: Pd0Pt100/HY>Pd100Pt0/HY>Pd33Pt67/HY. Atomic composition Pd/Pd+Pt equal to 0.33, and relative distribution of weak/strong acid sites equal to 2, favor hydrogenation of toluene to methylcyclohexane in metal sites and subsequent skeletal isomerization in the acidic sites through dimethylcyclopentane intermediate and ring-opening in the metal sites, leading to increased formation of n-heptane relative to iso-heptane. Bimetallic Pd-Pt/HY catalysts prepared by the co-impregnation method with an atomic variation of Pd/Pd+Pt were studied to convert toluene and methylcyclohexane. The catalysts were characterized by the BET method, chemisorption of CO by the pulse method, programmed temperature reduction (H2-TPR), and programmed ammonia thermo-desorption (NH3TPD). Results of chemisorption of CO and H2-TPR for Pd-Pt/HY catalysts suggest the existence of a strong interaction between Pd and Pt. The NH3-TPD showed that incorporating metals influences the percentage of relative distribution of weak/strong acid sites presented in decreasing order of acidity: Pd0Pt100/HY>Pd100Pt0/HY>Pd33Pt67/HY. Atomic composition Pd/Pd+Pt equal to 0.33, and relative distribution of weak/strong acid sites equal to 2, favor hydrogenation of toluene to methylcyclohexane in metal sites and subsequent skeletal isomerization in the acidic sites through dimethylcyclopentane intermediate and ring-opening in the metal sites, leading to increased formation of n-heptane relative to iso-heptane.","PeriodicalId":42183,"journal":{"name":"UIS Ingenierias","volume":" ","pages":""},"PeriodicalIF":0.3000,"publicationDate":"2023-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Toluene hydrogenation and ring-opening on bimetallic Pd-Pt/HY catalysts\",\"authors\":\"T. Romero, L. Melo, María Esparragoza, Rosarmy Ávila, A. Moronta, G. Carruyo, L. García, C. Donoso, Laura Sáenz, Carlos Yugcha-Pilamunga\",\"doi\":\"10.18273/revuin.v22n1-2023003\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Bimetallic Pd-Pt/HY catalysts prepared by the co-impregnation method with an atomic variation of Pd/Pd+Pt were studied to convert toluene and methylcyclohexane. The catalysts were characterized by the BET method, chemisorption of CO by the pulse method, programmed temperature reduction (H2-TPR), and programmed ammonia thermo-desorption (NH3TPD). Results of chemisorption of CO and H2-TPR for Pd-Pt/HY catalysts suggest the existence of a strong interaction between Pd and Pt. The NH3-TPD showed that incorporating metals influences the percentage of relative distribution of weak/strong acid sites presented in decreasing order of acidity: Pd0Pt100/HY>Pd100Pt0/HY>Pd33Pt67/HY. Atomic composition Pd/Pd+Pt equal to 0.33, and relative distribution of weak/strong acid sites equal to 2, favor hydrogenation of toluene to methylcyclohexane in metal sites and subsequent skeletal isomerization in the acidic sites through dimethylcyclopentane intermediate and ring-opening in the metal sites, leading to increased formation of n-heptane relative to iso-heptane. Bimetallic Pd-Pt/HY catalysts prepared by the co-impregnation method with an atomic variation of Pd/Pd+Pt were studied to convert toluene and methylcyclohexane. The catalysts were characterized by the BET method, chemisorption of CO by the pulse method, programmed temperature reduction (H2-TPR), and programmed ammonia thermo-desorption (NH3TPD). Results of chemisorption of CO and H2-TPR for Pd-Pt/HY catalysts suggest the existence of a strong interaction between Pd and Pt. 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Toluene hydrogenation and ring-opening on bimetallic Pd-Pt/HY catalysts
Bimetallic Pd-Pt/HY catalysts prepared by the co-impregnation method with an atomic variation of Pd/Pd+Pt were studied to convert toluene and methylcyclohexane. The catalysts were characterized by the BET method, chemisorption of CO by the pulse method, programmed temperature reduction (H2-TPR), and programmed ammonia thermo-desorption (NH3TPD). Results of chemisorption of CO and H2-TPR for Pd-Pt/HY catalysts suggest the existence of a strong interaction between Pd and Pt. The NH3-TPD showed that incorporating metals influences the percentage of relative distribution of weak/strong acid sites presented in decreasing order of acidity: Pd0Pt100/HY>Pd100Pt0/HY>Pd33Pt67/HY. Atomic composition Pd/Pd+Pt equal to 0.33, and relative distribution of weak/strong acid sites equal to 2, favor hydrogenation of toluene to methylcyclohexane in metal sites and subsequent skeletal isomerization in the acidic sites through dimethylcyclopentane intermediate and ring-opening in the metal sites, leading to increased formation of n-heptane relative to iso-heptane. Bimetallic Pd-Pt/HY catalysts prepared by the co-impregnation method with an atomic variation of Pd/Pd+Pt were studied to convert toluene and methylcyclohexane. The catalysts were characterized by the BET method, chemisorption of CO by the pulse method, programmed temperature reduction (H2-TPR), and programmed ammonia thermo-desorption (NH3TPD). Results of chemisorption of CO and H2-TPR for Pd-Pt/HY catalysts suggest the existence of a strong interaction between Pd and Pt. The NH3-TPD showed that incorporating metals influences the percentage of relative distribution of weak/strong acid sites presented in decreasing order of acidity: Pd0Pt100/HY>Pd100Pt0/HY>Pd33Pt67/HY. Atomic composition Pd/Pd+Pt equal to 0.33, and relative distribution of weak/strong acid sites equal to 2, favor hydrogenation of toluene to methylcyclohexane in metal sites and subsequent skeletal isomerization in the acidic sites through dimethylcyclopentane intermediate and ring-opening in the metal sites, leading to increased formation of n-heptane relative to iso-heptane.
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