生物质利用策略在新型聚合物和聚合物树脂生产中的应用

Q2 Materials Science
Justin J. Kosalka, G. Sacripante, A. Lough, D. Foucher, Robert A. Gossage
{"title":"生物质利用策略在新型聚合物和聚合物树脂生产中的应用","authors":"Justin J. Kosalka, G. Sacripante, A. Lough, D. Foucher, Robert A. Gossage","doi":"10.1177/204124791700800101","DOIUrl":null,"url":null,"abstract":"The synthesis and full characterisation, including in one case via single crystal X-ray diffraction, of two novel bio-derived aromatic monomers are reported. These materials, incorporating a Eugenol or Vanillin molecular skeleton are modified to incorporate diol chains obtained from reaction with glycerine carbonate. They are further characterised by the presence of other groups (e.g., allyl) which are also capable of engendering polymerisation. Facile heat induced self-polymerization is noted in one of the new monomers. The compounds are further tested in block co-polymer synthesis and found to form blocks with simple co-monomers such as succinic acid.","PeriodicalId":20353,"journal":{"name":"Polymers from Renewable Resources","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2017-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/204124791700800101","citationCount":"1","resultStr":"{\"title\":\"Biomass Utilisation Strategies for Applications in Novel Polymer and Polymer Resin Production\",\"authors\":\"Justin J. Kosalka, G. Sacripante, A. Lough, D. Foucher, Robert A. Gossage\",\"doi\":\"10.1177/204124791700800101\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The synthesis and full characterisation, including in one case via single crystal X-ray diffraction, of two novel bio-derived aromatic monomers are reported. These materials, incorporating a Eugenol or Vanillin molecular skeleton are modified to incorporate diol chains obtained from reaction with glycerine carbonate. They are further characterised by the presence of other groups (e.g., allyl) which are also capable of engendering polymerisation. Facile heat induced self-polymerization is noted in one of the new monomers. The compounds are further tested in block co-polymer synthesis and found to form blocks with simple co-monomers such as succinic acid.\",\"PeriodicalId\":20353,\"journal\":{\"name\":\"Polymers from Renewable Resources\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2017-02-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1177/204124791700800101\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymers from Renewable Resources\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1177/204124791700800101\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"Materials Science\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymers from Renewable Resources","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1177/204124791700800101","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Materials Science","Score":null,"Total":0}
引用次数: 1

摘要

本文报道了两种新型生物衍生芳香单体的合成和完整表征,包括单晶x射线衍射。这些含有丁香酚或香兰素分子骨架的材料经过修饰,加入了与碳酸甘油反应得到的二醇链。它们的进一步特征是存在同样能够产生聚合的其他基团(例如,烯丙基)。在一个新单体中发现了易热诱导自聚合。在嵌段共聚物合成中进一步测试了这些化合物,发现它们与简单的共单体如琥珀酸形成嵌段。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Biomass Utilisation Strategies for Applications in Novel Polymer and Polymer Resin Production
The synthesis and full characterisation, including in one case via single crystal X-ray diffraction, of two novel bio-derived aromatic monomers are reported. These materials, incorporating a Eugenol or Vanillin molecular skeleton are modified to incorporate diol chains obtained from reaction with glycerine carbonate. They are further characterised by the presence of other groups (e.g., allyl) which are also capable of engendering polymerisation. Facile heat induced self-polymerization is noted in one of the new monomers. The compounds are further tested in block co-polymer synthesis and found to form blocks with simple co-monomers such as succinic acid.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Polymers from Renewable Resources
Polymers from Renewable Resources Materials Science-Polymers and Plastics
CiteScore
3.50
自引率
0.00%
发文量
15
期刊介绍: Polymers from Renewable Resources, launched in 2010, publishes leading peer reviewed research that is focused on the development of renewable polymers and their application in the production of industrial, consumer, and medical products. The progressive decline of fossil resources, together with the ongoing increases in oil prices, has initiated an increase in the search for alternatives based on renewable resources for the production of energy. The prevalence of petroleum and carbon based chemistry for the production of organic chemical goods has generated a variety of initiatives aimed at replacing fossil sources with renewable counterparts. In particular, major efforts are being conducted in polymer science and technology to prepare macromolecular materials based on renewable resources. Also gaining momentum is the utilisation of vegetable biomass either by the separation of its components and their development or after suitable chemical modification. This journal is a valuable addition to academic, research and industrial libraries, research institutions dealing with the use of natural resources and materials science and industrial laboratories concerned with polymer science.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信