水葫芦生物质与煤共燃结渣特性研究

IF 0.8 4区 工程技术 Q4 CHEMISTRY, MULTIDISCIPLINARY
Zhenrong Liu, Yuwei Hu, Junhua Wang, Junquan Meng, Yancheng Zhang, Rong Chen
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引用次数: 1

摘要

由于煤燃烧发电造成的污染和生物质直接燃烧发电综合效率低,生物质与煤共燃发电已成为未来的发展趋势。为了减轻煤与水葫芦共燃发电实际生产中结渣的危害,结合结渣判别指标,采用x射线荧光(XRF)和x射线衍射(XRD)技术,研究了混合比例、温度和添加剂对水葫芦混合无烟煤燃烧结渣特性的影响。在较高的灰化温度下,降低了灰中K和Cl的含量,有助于减少结渣。CaO可以与燃料中的K竞争,并优先与Si和Al反应,导致KAlSiO4和KAlSi3O8的产量减少。高岭石可以削弱K作为Cl载体的作用,使K与Si、Al形成复杂的钾铝硅酸盐。综合分析6个灰样结渣指标,水葫芦灰分重度结渣,无烟煤灰分中度结渣,水葫芦与煤共燃可在一定程度上改变灰分结渣程度。高岭土对混合灰结渣的抑制效果优于CaO。这些发现为用煤燃烧水生生物质提供了一个起点。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Slagging Characteristics of Co-Combustion of Water Hyacinth Biomass and Coal

Slagging Characteristics of Co-Combustion of Water Hyacinth Biomass and Coal

Due to the pollution caused by coal combustion for power generation and the low comprehensive efficiency of biomass direct combustion for power generation, biomass and coal co-combustion for power generation has become the future development trend. To mitigate the hazards of slagging in the actual production of coal and water hyacinth co-combustion for power generation, combined with slagging discrimination indices, X-ray fluorescence (XRF) and X-ray diffraction (XRD) were applied to study the effects of mixing ratios, temperature, and additives on the slagging characteristics of water hyacinth mixed anthracite combustion. At higher ashing temperatures, the K and Cl content in the ash was reduced, which helped to reduce slagging. CaO can compete with the fuel’s K and react preferentially with Si and Al, leading to reduced production of KAlSiO4 and KAlSi3O8. Kaolinite can weaken the function of K as a Cl carrier, allowing K to form complex potassium aluminosilicates with Si and Al. According to the comprehensive analysis of six ash sample slagging indexes, water hyacinth ash is serious slagging, anthracite ash is medium slagging, and the co-combustion of water hyacinth and coal can change the degree of ash slagging to a certain extent. Kaolin has a better-mitigating effect than CaO in preventing the slagging of mixed ash. These findings provide a starting point for the combustion of aquatic biomass with coal.

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来源期刊
Solid Fuel Chemistry
Solid Fuel Chemistry CHEMISTRY, MULTIDISCIPLINARY-ENERGY & FUELS
CiteScore
1.10
自引率
28.60%
发文量
52
审稿时长
6-12 weeks
期刊介绍: The journal publishes theoretical and applied articles on the chemistry and physics of solid fuels and carbonaceous materials. It addresses the composition, structure, and properties of solid fuels. The aim of the published articles is to demonstrate how novel discoveries, developments, and theories may be used in improved analysis and design of new types of fuels, chemicals, and by-products. The journal is particularly concerned with technological aspects of various chemical conversion processes and includes papers related to geochemistry, petrology and systematization of fossil fuels, their beneficiation and preparation for processing, the processes themselves, and the ultimate recovery of the liquid or gaseous end products.
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