{"title":"二硫代氰基-N-双[8-（二苯基膦）-喹啉]钌的合成、光谱性质和单晶X射线结构（Ⅱ）","authors":"","doi":"10.47014/17.2.3","DOIUrl":null,"url":null,"abstract":"The new ruthenium complex, [Ru(N-P)2(SCN)2], where N-P = 8-(diphenylphosphino)quinoline, was prepared and characterized by FT-IR, UV-Vis spectrometry and X-ray crystallography. The complex crystallized in the monoclinic system with the space group P1211. The cell parameters are a = 9.9635(7) Å, b = 18.8967(9) Å, c = 11.2651(6) Å, α = γ = 90, β = 110.474(7) . The complex has a distorted octahedral structure with cis configuration for the thiocyanate groups. The bond-length analysis indicates the following order of trans-influence: P > N(SCN-) > N(quinolone).","PeriodicalId":14654,"journal":{"name":"Jordan Journal of Chemistry","volume":"1 1","pages":""},"PeriodicalIF":0.4000,"publicationDate":"2022-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Synthesis, Spectroscopic Properties and Single Crystal X-ray Structure of Dithiocyanato-N-bis[8-(diphenylphosphino)-quinoline]ruthenium(II)\",\"authors\":\"\",\"doi\":\"10.47014/17.2.3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The new ruthenium complex, [Ru(N-P)2(SCN)2], where N-P = 8-(diphenylphosphino)quinoline, was prepared and characterized by FT-IR, UV-Vis spectrometry and X-ray crystallography. The complex crystallized in the monoclinic system with the space group P1211. The cell parameters are a = 9.9635(7) Å, b = 18.8967(9) Å, c = 11.2651(6) Å, α = γ = 90, β = 110.474(7) . The complex has a distorted octahedral structure with cis configuration for the thiocyanate groups. The bond-length analysis indicates the following order of trans-influence: P > N(SCN-) > N(quinolone).\",\"PeriodicalId\":14654,\"journal\":{\"name\":\"Jordan Journal of Chemistry\",\"volume\":\"1 1\",\"pages\":\"\"},\"PeriodicalIF\":0.4000,\"publicationDate\":\"2022-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Jordan Journal of Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.47014/17.2.3\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Jordan Journal of Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.47014/17.2.3","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Synthesis, Spectroscopic Properties and Single Crystal X-ray Structure of Dithiocyanato-N-bis[8-(diphenylphosphino)-quinoline]ruthenium(II)
The new ruthenium complex, [Ru(N-P)2(SCN)2], where N-P = 8-(diphenylphosphino)quinoline, was prepared and characterized by FT-IR, UV-Vis spectrometry and X-ray crystallography. The complex crystallized in the monoclinic system with the space group P1211. The cell parameters are a = 9.9635(7) Å, b = 18.8967(9) Å, c = 11.2651(6) Å, α = γ = 90, β = 110.474(7) . The complex has a distorted octahedral structure with cis configuration for the thiocyanate groups. The bond-length analysis indicates the following order of trans-influence: P > N(SCN-) > N(quinolone).
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