{"title":"聚(2,6-二甲基-1,4-苯氧基)非对称中空纤维气体分离膜的制备","authors":"A. V. Varezhkin","doi":"10.1134/S2517751623010079","DOIUrl":null,"url":null,"abstract":"<p>The regularities of manufacturing hollow fiber membranes made of poly(2,6-dimethylphenylene-1,4-oxide) (PPO) for gas separation have been studied. The phase inversion method has been used to manufacture the membranes. The dependence of the separation characteristics of the membrane on such spinning parameters as the type of solvent, the exposure time of the polymer solution in the “air” gap, and the type of non-solvents (coagulants) has been studied. The characteristics of the membrane have been obtained by determining their gas permeability. It is shown that higher separation and gas transport characteristics of the PPO membrane are obtained using the wet spinning method. An intrinsic selectivity of 4.8 ± 0.4 has been obtained at a specific oxygen permeability (20°C) of (<i>P</i>/<i>l</i>) (790 ± 82) × 10<sup>–9</sup> [m<sup>3</sup> (STP) m<sup>–2</sup> s<sup>–1</sup> kPa] for oxygen-nitrogen system. The developed membranes are promising for use in case for producing nitrogen and oxygen-enriched air.</p>","PeriodicalId":700,"journal":{"name":"Membranes and Membrane Technologies","volume":"5 1","pages":"27 - 34"},"PeriodicalIF":2.0000,"publicationDate":"2023-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Manufacturing of Asymmetric Hollow Fiber Membranes for Gas Separation Made of Poly(2,6-Dimethyl-1,4-Phenylenoxide)\",\"authors\":\"A. V. Varezhkin\",\"doi\":\"10.1134/S2517751623010079\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The regularities of manufacturing hollow fiber membranes made of poly(2,6-dimethylphenylene-1,4-oxide) (PPO) for gas separation have been studied. The phase inversion method has been used to manufacture the membranes. The dependence of the separation characteristics of the membrane on such spinning parameters as the type of solvent, the exposure time of the polymer solution in the “air” gap, and the type of non-solvents (coagulants) has been studied. The characteristics of the membrane have been obtained by determining their gas permeability. It is shown that higher separation and gas transport characteristics of the PPO membrane are obtained using the wet spinning method. An intrinsic selectivity of 4.8 ± 0.4 has been obtained at a specific oxygen permeability (20°C) of (<i>P</i>/<i>l</i>) (790 ± 82) × 10<sup>–9</sup> [m<sup>3</sup> (STP) m<sup>–2</sup> s<sup>–1</sup> kPa] for oxygen-nitrogen system. The developed membranes are promising for use in case for producing nitrogen and oxygen-enriched air.</p>\",\"PeriodicalId\":700,\"journal\":{\"name\":\"Membranes and Membrane Technologies\",\"volume\":\"5 1\",\"pages\":\"27 - 34\"},\"PeriodicalIF\":2.0000,\"publicationDate\":\"2023-04-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Membranes and Membrane Technologies\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S2517751623010079\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Membranes and Membrane Technologies","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1134/S2517751623010079","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Manufacturing of Asymmetric Hollow Fiber Membranes for Gas Separation Made of Poly(2,6-Dimethyl-1,4-Phenylenoxide)
The regularities of manufacturing hollow fiber membranes made of poly(2,6-dimethylphenylene-1,4-oxide) (PPO) for gas separation have been studied. The phase inversion method has been used to manufacture the membranes. The dependence of the separation characteristics of the membrane on such spinning parameters as the type of solvent, the exposure time of the polymer solution in the “air” gap, and the type of non-solvents (coagulants) has been studied. The characteristics of the membrane have been obtained by determining their gas permeability. It is shown that higher separation and gas transport characteristics of the PPO membrane are obtained using the wet spinning method. An intrinsic selectivity of 4.8 ± 0.4 has been obtained at a specific oxygen permeability (20°C) of (P/l) (790 ± 82) × 10–9 [m3 (STP) m–2 s–1 kPa] for oxygen-nitrogen system. The developed membranes are promising for use in case for producing nitrogen and oxygen-enriched air.
期刊介绍：
The journal Membranes and Membrane Technologies publishes original research articles and reviews devoted to scientific research and technological advancements in the field of membranes and membrane technologies, including the following main topics:novel membrane materials and creation of highly efficient polymeric and inorganic membranes;hybrid membranes, nanocomposites, and nanostructured membranes;aqueous and nonaqueous filtration processes (micro-, ultra-, and nanofiltration; reverse osmosis);gas separation;electromembrane processes and fuel cells;membrane pervaporation and membrane distillation;membrane catalysis and membrane reactors;water desalination and wastewater treatment;hybrid membrane processes;membrane sensors;membrane extraction and membrane emulsification;mathematical simulation of porous structures and membrane separation processes;membrane characterization;membrane technologies in industry (energy, mineral extraction, pharmaceutics and medicine, chemistry and petroleum chemistry, food industry, and others);membranes and protection of environment (“green chemistry”).The journal has been published in Russian already for several years, English translations of the content used to be integrated in the journal Petroleum Chemistry. This journal is a split off with additional topics.
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