Wellington Tafireyi, Max Littlewood, H. C. H. Bandulasena, A. Trybala, V. Starov
{"title":"疏水性多孔基质上的超扩散表面活性剂","authors":"Wellington Tafireyi, Max Littlewood, H. C. H. Bandulasena, A. Trybala, V. Starov","doi":"10.3390/colloids7020038","DOIUrl":null,"url":null,"abstract":"The wetting behavior of droplets of aqueous surfactant solutions over hydrophobic thin PVDF porous membrane and non-porous hydrophobic PVDF film is investigated for small (~10 μL) droplets of aqueous trisiloxane surfactant solutions: superspreader S 240. The time dependencies of contact angle, droplet radius, wetted area and volume were monitored as well as penetration into the porous substrate. It is shown that the fast spreading of droplets of trisiloxane solutions takes place both in the case of porous and non-porous substrates at a concentration above some critical concentration. It was found that the trisiloxane droplets penetrate into the hydrophobic porous substrates and disappear much faster than on a corresponding hydrophobic non-porous substrate, which was not observed before. This phenomenon is referred to as “superpenetration”.","PeriodicalId":10433,"journal":{"name":"Colloids and Interfaces","volume":null,"pages":null},"PeriodicalIF":2.5000,"publicationDate":"2023-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Superspreading Surfactant on Hydrophobic Porous Substrates\",\"authors\":\"Wellington Tafireyi, Max Littlewood, H. C. H. Bandulasena, A. Trybala, V. Starov\",\"doi\":\"10.3390/colloids7020038\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The wetting behavior of droplets of aqueous surfactant solutions over hydrophobic thin PVDF porous membrane and non-porous hydrophobic PVDF film is investigated for small (~10 μL) droplets of aqueous trisiloxane surfactant solutions: superspreader S 240. The time dependencies of contact angle, droplet radius, wetted area and volume were monitored as well as penetration into the porous substrate. It is shown that the fast spreading of droplets of trisiloxane solutions takes place both in the case of porous and non-porous substrates at a concentration above some critical concentration. It was found that the trisiloxane droplets penetrate into the hydrophobic porous substrates and disappear much faster than on a corresponding hydrophobic non-porous substrate, which was not observed before. This phenomenon is referred to as “superpenetration”.\",\"PeriodicalId\":10433,\"journal\":{\"name\":\"Colloids and Interfaces\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.5000,\"publicationDate\":\"2023-05-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Colloids and Interfaces\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.3390/colloids7020038\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Colloids and Interfaces","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.3390/colloids7020038","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Superspreading Surfactant on Hydrophobic Porous Substrates
The wetting behavior of droplets of aqueous surfactant solutions over hydrophobic thin PVDF porous membrane and non-porous hydrophobic PVDF film is investigated for small (~10 μL) droplets of aqueous trisiloxane surfactant solutions: superspreader S 240. The time dependencies of contact angle, droplet radius, wetted area and volume were monitored as well as penetration into the porous substrate. It is shown that the fast spreading of droplets of trisiloxane solutions takes place both in the case of porous and non-porous substrates at a concentration above some critical concentration. It was found that the trisiloxane droplets penetrate into the hydrophobic porous substrates and disappear much faster than on a corresponding hydrophobic non-porous substrate, which was not observed before. This phenomenon is referred to as “superpenetration”.