A. A. Zgliui, M. S. Tivanov, N. N. Curmei, L. V. Dermenji, L. I. Bruc, D. A. Serban
{"title":"喷雾热解法制备含银Cu2ZnSnS4薄膜的结构","authors":"A. A. Zgliui, M. S. Tivanov, N. N. Curmei, L. V. Dermenji, L. I. Bruc, D. A. Serban","doi":"10.3103/S0003701X23600790","DOIUrl":null,"url":null,"abstract":"<p>Kesterite Cu<sub>2</sub>ZnSnS<sub>4</sub> thin films were synthesized by the spray pyrolysis method with subsequent annealing at temperatures in the range from 425 to 525°C. To understand the impact of Ag on the Cu<sub>2</sub>ZnSnS<sub>4</sub> structural properties, changes in the elemental and phase composition, as well as microstructure were studied by electron microanalysis, X-ray phase and Raman analysis, scanning probe microscopy and scanning electron microscopy. The obtained samples have a compact morphology without appreciable voids and pores and crystallize in the tetragonal structure of kesterite CZTS. Phase analysis indicated incorporation of Ag in different concentrations without formation of other impurity compounds. An increase in the annealing temperature leads to an increase in the coherent scattering region, while the stoichiometric ratio of metals to chalcogen approaches 1, remaining close to that upon Ag alloying.</p>","PeriodicalId":475,"journal":{"name":"Applied Solar Energy","volume":null,"pages":null},"PeriodicalIF":1.2040,"publicationDate":"2023-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Structure of Ag-Containing Cu2ZnSnS4 Thin Films, Obtained by Spray Pyrolysis\",\"authors\":\"A. A. Zgliui, M. S. Tivanov, N. N. Curmei, L. V. Dermenji, L. I. Bruc, D. A. Serban\",\"doi\":\"10.3103/S0003701X23600790\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Kesterite Cu<sub>2</sub>ZnSnS<sub>4</sub> thin films were synthesized by the spray pyrolysis method with subsequent annealing at temperatures in the range from 425 to 525°C. To understand the impact of Ag on the Cu<sub>2</sub>ZnSnS<sub>4</sub> structural properties, changes in the elemental and phase composition, as well as microstructure were studied by electron microanalysis, X-ray phase and Raman analysis, scanning probe microscopy and scanning electron microscopy. The obtained samples have a compact morphology without appreciable voids and pores and crystallize in the tetragonal structure of kesterite CZTS. Phase analysis indicated incorporation of Ag in different concentrations without formation of other impurity compounds. An increase in the annealing temperature leads to an increase in the coherent scattering region, while the stoichiometric ratio of metals to chalcogen approaches 1, remaining close to that upon Ag alloying.</p>\",\"PeriodicalId\":475,\"journal\":{\"name\":\"Applied Solar Energy\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.2040,\"publicationDate\":\"2023-10-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Solar Energy\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://link.springer.com/article/10.3103/S0003701X23600790\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"Energy\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Solar Energy","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.3103/S0003701X23600790","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Energy","Score":null,"Total":0}
Structure of Ag-Containing Cu2ZnSnS4 Thin Films, Obtained by Spray Pyrolysis
Kesterite Cu2ZnSnS4 thin films were synthesized by the spray pyrolysis method with subsequent annealing at temperatures in the range from 425 to 525°C. To understand the impact of Ag on the Cu2ZnSnS4 structural properties, changes in the elemental and phase composition, as well as microstructure were studied by electron microanalysis, X-ray phase and Raman analysis, scanning probe microscopy and scanning electron microscopy. The obtained samples have a compact morphology without appreciable voids and pores and crystallize in the tetragonal structure of kesterite CZTS. Phase analysis indicated incorporation of Ag in different concentrations without formation of other impurity compounds. An increase in the annealing temperature leads to an increase in the coherent scattering region, while the stoichiometric ratio of metals to chalcogen approaches 1, remaining close to that upon Ag alloying.
期刊介绍:
Applied Solar Energy is an international peer reviewed journal covers various topics of research and development studies on solar energy conversion and use: photovoltaics, thermophotovoltaics, water heaters, passive solar heating systems, drying of agricultural production, water desalination, solar radiation condensers, operation of Big Solar Oven, combined use of solar energy and traditional energy sources, new semiconductors for solar cells and thermophotovoltaic system photocells, engines for autonomous solar stations.