Andrei Munteanu, Tomáš Plachý, Lenka Munteanu, Fahanwi Asabuwa Ngwabebhoh, Jaroslav Stejskal, Miroslava Trchová, Michal Kubík, Michal Sedlačík
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Bidisperse magnetorheological fluids utilizing composite polypyrrole nanotubes/magnetite nanoparticles and carbonyl iron microspheres
Conductive polypyrrole nanotubes were synthesized with a two-step one-pot synthesis. During synthesis, the nanotubes were decorated with magnetite nanoparticles at different concentrations granting them magnetic properties. The characterization of the tubes revealed differences from the theoretical reactions. A bidisperse magnetorheological fluid (MRF) was prepared by mixing the composite polypyrrole nanotubes/magnetite nanoparticles with commercial carbonyl iron spherical microparticles in silicone oil. The rheological properties of the bidisperse system were studied under the presence of magnetic field at room and elevated temperature. An enhancement of the MR effect with the presence of the nanotubes was observed when compared with a standard MRF consisted only of magnetic microparticles. Due to the faster magnetic saturation of the nanotubes, this enhancement is exceptionally high at low magnetic fields. The stability of the system is studied under dynamic conditions where it is revealed that the nanotubes keep the standard particles well dispersed with the sedimentation improving by more than 50%.
期刊介绍：
"Rheologica Acta is the official journal of The European Society of Rheology. The aim of the journal is to advance the science of rheology, by publishing high quality peer reviewed articles, invited reviews and peer reviewed short communications.
The Scope of Rheologica Acta includes:
- Advances in rheometrical and rheo-physical techniques, rheo-optics, microrheology
- Rheology of soft matter systems, including polymer melts and solutions, colloidal dispersions, cement, ceramics, glasses, gels, emulsions, surfactant systems, liquid crystals, biomaterials and food.
- Rheology of Solids, chemo-rheology
- Electro and magnetorheology
- Theory of rheology
- Non-Newtonian fluid mechanics, complex fluids in microfluidic devices and flow instabilities
- Interfacial rheology
Rheologica Acta aims to publish papers which represent a substantial advance in the field, mere data reports or incremental work will not be considered. Priority will be given to papers that are methodological in nature and are beneficial to a wide range of material classes. It should also be noted that the list of topics given above is meant to be representative, not exhaustive. The editors welcome feedback on the journal and suggestions for reviews and comments."
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