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无添加剂，n -杂环氮催化光还原环酮肟酯†

Organic chemistry frontiers : an international journal of organic chemistry Pub Date : 2023-01-01 DOI:10.1039/d2qo01961b
Xiao-Di Su , Zhu-Sheng Yang , Wei Gong , Zhi-Xiang Wang , Xiang-Yu Chen
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引用次数: 0

摘要

我们报道了在不存在任何添加剂的情况下，N-杂环氮（NHN）可以用作理想的电荷转移络合物催化剂，用于环酮肟酯的光活化，其中NHN阳离子充当催化电子受体，反离子I−是催化电子供体。这种策略能够合成各种三取代烯烃和杂环。
本文章由计算机程序翻译，如有差异，请以英文原文为准。

Additive free, N-heterocyclic nitrenium catalyzed photoreduction of cycloketone oxime esters†

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Additive free, N-heterocyclic nitrenium catalyzed photoreduction of cycloketone oxime esters†
We report that N-heterocyclic nitreniums (NHNs) can be used as ideal charge transfer complex catalysts in the absence of any additives for the photoactivation of cycloketone oxime esters, where the...
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Organic chemistry frontiers : an international journal of organic chemistry
Organic chemistry frontiers : an international journal of organic chemistry
CiteScore
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