{"title":"吩噻嗪、二氢吩嗪和吩恶嗪:贵金属基光氧化还原催化剂的可持续替代品。","authors":"Daniel A Corbin, Chern-Hooi Lim, Garret M Miyake","doi":"","DOIUrl":null,"url":null,"abstract":"<p><p>The application of photoredox catalysis to atom-transfer radical polymerization (ATRP) has resulted in the development of strongly reducing organic photoredox catalysts (PCs) that are some of the most reducing catalysts known. The objectives of this review are to highlight these PCs with regard to their development and applications in polymer and organic synthesis, as well illuminate aspects of these PCs that remain to be studied further.</p>","PeriodicalId":50829,"journal":{"name":"Aldrichimica Acta","volume":null,"pages":null},"PeriodicalIF":2.2000,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6910655/pdf/nihms-1026916.pdf","citationCount":"0","resultStr":"{\"title\":\"Phenothiazines, Dihydrophenazines, and Phenoxazines: Sustainable Alternatives to Precious-Metal-Based Photoredox Catalysts.\",\"authors\":\"Daniel A Corbin, Chern-Hooi Lim, Garret M Miyake\",\"doi\":\"\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>The application of photoredox catalysis to atom-transfer radical polymerization (ATRP) has resulted in the development of strongly reducing organic photoredox catalysts (PCs) that are some of the most reducing catalysts known. The objectives of this review are to highlight these PCs with regard to their development and applications in polymer and organic synthesis, as well illuminate aspects of these PCs that remain to be studied further.</p>\",\"PeriodicalId\":50829,\"journal\":{\"name\":\"Aldrichimica Acta\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2019-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6910655/pdf/nihms-1026916.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Aldrichimica Acta\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Aldrichimica Acta","FirstCategoryId":"92","ListUrlMain":"","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
Phenothiazines, Dihydrophenazines, and Phenoxazines: Sustainable Alternatives to Precious-Metal-Based Photoredox Catalysts.
The application of photoredox catalysis to atom-transfer radical polymerization (ATRP) has resulted in the development of strongly reducing organic photoredox catalysts (PCs) that are some of the most reducing catalysts known. The objectives of this review are to highlight these PCs with regard to their development and applications in polymer and organic synthesis, as well illuminate aspects of these PCs that remain to be studied further.
期刊介绍:
For over 50 years, the Aldrichimica Acta has been a leading, open-access, international forum for the frontiers of chemical research. It publishes topical and insightful reviews, written by prominent chemists from around the world and covering a variety of topics usually based on a synthetic theme in organic, organometallic, and bio-organic chemistry.