BODIPY二极体和三极体:合成、光学、电化学和晶体管性能。

Q1 Chemistry

Chemistry Central Journal Pub Date : 2018-05-11 DOI:10.1186/s13065-018-0430-5

Sompit Wanwong, Piyachai Khomein, S Thayumanavan

{"title":"BODIPY二极体和三极体:合成、光学、电化学和晶体管性能。","authors":"Sompit Wanwong, Piyachai Khomein, S Thayumanavan","doi":"10.1186/s13065-018-0430-5","DOIUrl":null,"url":null,"abstract":"A series of D-A dyads and D-A-D triads molecular systems based on triphenylamine and 9-ethyl-carbarzole as donor (D) and BODIPY as acceptor (A) has been designed and synthesized. The optoelectronic properties including optical, electrochemical, and charge carrier mobility of these molecules have been investigated. We found that the D-A-D triads exhibited broader absorption, raising the HOMO energy levels and increase hole carrier mobilities. Analysis surface morphology revealed that BODIPY containing carbazole demonstrated smooth film and no macro phase aggregation was observed upon thermal annealing.","PeriodicalId":9842,"journal":{"name":"Chemistry Central Journal","volume":"12 1","pages":"60"},"PeriodicalIF":0.0000,"publicationDate":"2018-05-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1186/s13065-018-0430-5","citationCount":"9","resultStr":"{\"title\":\"BODIPY dyads and triads: synthesis, optical, electrochemical and transistor properties.\",\"authors\":\"Sompit Wanwong, Piyachai Khomein, S Thayumanavan\",\"doi\":\"10.1186/s13065-018-0430-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A series of D-A dyads and D-A-D triads molecular systems based on triphenylamine and 9-ethyl-carbarzole as donor (D) and BODIPY as acceptor (A) has been designed and synthesized. The optoelectronic properties including optical, electrochemical, and charge carrier mobility of these molecules have been investigated. We found that the D-A-D triads exhibited broader absorption, raising the HOMO energy levels and increase hole carrier mobilities. Analysis surface morphology revealed that BODIPY containing carbazole demonstrated smooth film and no macro phase aggregation was observed upon thermal annealing.\",\"PeriodicalId\":9842,\"journal\":{\"name\":\"Chemistry Central Journal\",\"volume\":\"12 1\",\"pages\":\"60\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2018-05-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1186/s13065-018-0430-5\",\"citationCount\":\"9\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry Central Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1186/s13065-018-0430-5\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"Chemistry\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry Central Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1186/s13065-018-0430-5","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Chemistry","Score":null,"Total":0}

引用次数: 9

摘要

设计合成了以三苯胺和9-乙基卡巴唑为供体(D)， BODIPY为受体(A)的一系列D-A二联体和D-A-D三联体分子体系。研究了这些分子的光电性质，包括光学、电化学和载流子迁移率。我们发现，D-A-D三元组表现出更广泛的吸收，提高了HOMO能级，增加了空穴载流子迁移率。表面形貌分析表明，含咔唑的BODIPY薄膜光滑，热处理后无宏观相聚集现象。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

BODIPY dyads and triads: synthesis, optical, electrochemical and transistor properties.

查看原文本刊更多论文

BODIPY dyads and triads: synthesis, optical, electrochemical and transistor properties.

A series of D-A dyads and D-A-D triads molecular systems based on triphenylamine and 9-ethyl-carbarzole as donor (D) and BODIPY as acceptor (A) has been designed and synthesized. The optoelectronic properties including optical, electrochemical, and charge carrier mobility of these molecules have been investigated. We found that the D-A-D triads exhibited broader absorption, raising the HOMO energy levels and increase hole carrier mobilities. Analysis surface morphology revealed that BODIPY containing carbazole demonstrated smooth film and no macro phase aggregation was observed upon thermal annealing.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Chemistry Central Journal 化学-化学综合

CiteScore

4.40

自引率

0.00%

发文量

审稿时长

3.5 months

期刊介绍： BMC Chemistry is an open access, peer reviewed journal that considers all articles in the broad field of chemistry, including research on fundamental concepts, new developments and the application of chemical sciences to broad range of research fields, industry, and other disciplines. It provides an inclusive platform for the dissemination and discussion of chemistry to aid the advancement of all areas of research. Sections: -Analytical Chemistry -Organic Chemistry -Environmental and Energy Chemistry -Agricultural and Food Chemistry -Inorganic Chemistry -Medicinal Chemistry -Physical Chemistry -Materials and Macromolecular Chemistry -Green and Sustainable Chemistry