钌催化烯烃氢甲酰化-氢化-酯化反应

IF 4.4 3区化学 Q2 CHEMISTRY, PHYSICAL

Catalysis Science & Technology Pub Date : 2021-08-17 DOI:10.1039/D1CY01113H

Ricarda Dühren, Peter Kucmierczyk, Carolin Schneider, Ralf Jackstell, Robert Franke and Matthias Beller

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引用次数: 2

摘要

报道了一种新的催化骨牌还原烯烃氢甲酰化酯化反应。最佳方案是使用廉价的钌羰基催化剂，并使用醋酸作为溶剂和反应物。一般来说，使用脂肪烯烃或芳烃，包括工业上相关的二异丁烯，可以获得中等到较高的收率。这种原子高效的催化转化提供了从未官能化烯烃直接获得各种乙酸酯的途径。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Ruthenium-catalysed domino hydroformylation–hydrogenation–esterification of olefins†

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Ruthenium-catalysed domino hydroformylation–hydrogenation–esterification of olefins†

A novel catalytic domino reductive hydroformylation–esterification of olefins is reported. The optimal protocol makes use of an inexpensive Ru carbonyl catalyst and uses acetic acid as both solvent and reactant. In general, moderate to good yields are obtained using aliphatic or aromatic olefins including industrially relevant di-isobutene. This atom-efficient catalytic transformation provides straightforward access to various acetate esters from unfunctionalized olefins.

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来源期刊

Catalysis Science & Technology CHEMISTRY, PHYSICAL-

CiteScore

8.70

自引率

6.00%

发文量

587

审稿时长

1.5 months

期刊介绍： A multidisciplinary journal focusing on cutting edge research across all fundamental science and technological aspects of catalysis. Editor-in-chief: Bert Weckhuysen Impact factor: 5.0 Time to first decision (peer reviewed only): 31 days