{"title":"[1,2-双-（二苯基-膦基）苯]-七羰基二-μ-氢-（μ3-2,4,6-三甲基-苯基-亚膦基）-三角三钌的晶体结构。","authors":"Taeko Kakizawa","doi":"10.1107/S2056989017007770","DOIUrl":null,"url":null,"abstract":"<p><p>The title trinuclear ruthenium cluster, [Ru<sub>3</sub>(C<sub>30</sub>H<sub>24</sub>P<sub>2</sub>)(C<sub>9</sub>H<sub>11</sub>P)(CO)<sub>7</sub>(μ-H)<sub>2</sub>], has a triangular Ru<sub>3</sub> core that is capped with a mesitylphosphin-idene ligand, μ<sub>3</sub>-PMes (Mes = mesityl = 2,4,6-tri-methyl-phen-yl). The 1,2-bis-(di-phenyl-phosphan-yl)benzene mol-ecule acts as a bidentate phosphine ligand <i>via</i> two P atoms connecting to a single Ru atom. The title compound crystallizes with two independent mol-ecules in the asymmetric unit.</p>","PeriodicalId":7015,"journal":{"name":"Acta Crystallographica Section E Crystallographic Communications","volume":" ","pages":"945-948"},"PeriodicalIF":0.0000,"publicationDate":"2017-06-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1107/S2056989017007770","citationCount":"0","resultStr":"{\"title\":\"Crystal structure of [1,2-bis-(di-phenyl-phosphan-yl)benzene]-hepta-carbonyldi-μ-hydrido-(μ<sub>3</sub>-2,4,6-tri-methyl-phenyl-phosphin-idene)-<i>triangulo</i>-triruthenium.\",\"authors\":\"Taeko Kakizawa\",\"doi\":\"10.1107/S2056989017007770\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>The title trinuclear ruthenium cluster, [Ru<sub>3</sub>(C<sub>30</sub>H<sub>24</sub>P<sub>2</sub>)(C<sub>9</sub>H<sub>11</sub>P)(CO)<sub>7</sub>(μ-H)<sub>2</sub>], has a triangular Ru<sub>3</sub> core that is capped with a mesitylphosphin-idene ligand, μ<sub>3</sub>-PMes (Mes = mesityl = 2,4,6-tri-methyl-phen-yl). The 1,2-bis-(di-phenyl-phosphan-yl)benzene mol-ecule acts as a bidentate phosphine ligand <i>via</i> two P atoms connecting to a single Ru atom. The title compound crystallizes with two independent mol-ecules in the asymmetric unit.</p>\",\"PeriodicalId\":7015,\"journal\":{\"name\":\"Acta Crystallographica Section E Crystallographic Communications\",\"volume\":\" \",\"pages\":\"945-948\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2017-06-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1107/S2056989017007770\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Acta Crystallographica Section E Crystallographic Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1107/S2056989017007770\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2017/7/1 0:00:00\",\"PubModel\":\"eCollection\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Acta Crystallographica Section E Crystallographic Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1107/S2056989017007770","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2017/7/1 0:00:00","PubModel":"eCollection","JCR":"","JCRName":"","Score":null,"Total":0}
Crystal structure of [1,2-bis-(di-phenyl-phosphan-yl)benzene]-hepta-carbonyldi-μ-hydrido-(μ3-2,4,6-tri-methyl-phenyl-phosphin-idene)-triangulo-triruthenium.
The title trinuclear ruthenium cluster, [Ru3(C30H24P2)(C9H11P)(CO)7(μ-H)2], has a triangular Ru3 core that is capped with a mesitylphosphin-idene ligand, μ3-PMes (Mes = mesityl = 2,4,6-tri-methyl-phen-yl). The 1,2-bis-(di-phenyl-phosphan-yl)benzene mol-ecule acts as a bidentate phosphine ligand via two P atoms connecting to a single Ru atom. The title compound crystallizes with two independent mol-ecules in the asymmetric unit.
![Crystal structure of [1,2-bis-(di-phenyl-phosphan-yl)benzene]-hepta-carbonyldi-μ-hydrido-(μ<sub>3</sub>-2,4,6-tri-methyl-phenyl-phosphin-idene)-<i>triangulo</i>-triruthenium.](https://img.booksci.cn/booksciimg/2017-6/2023110278252599297069173143532.jpg)
![Crystal structure of [1,2-bis-(di-phenyl-phosphan-yl)benzene]-hepta-carbonyldi-μ-hydrido-(μ<sub>3</sub>-2,4,6-tri-methyl-phenyl-phosphin-idene)-<i>triangulo</i>-triruthenium.](https://img.booksci.cn/booksciimg/2017-6/2023110278254146859267376701553.jpg)
![Crystal structure of [1,2-bis-(di-phenyl-phosphan-yl)benzene]-hepta-carbonyldi-μ-hydrido-(μ<sub>3</sub>-2,4,6-tri-methyl-phenyl-phosphin-idene)-<i>triangulo</i>-triruthenium.](https://img.booksci.cn/booksciimg/2017-6/2023110278297800409810130848499.jpg)
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