{"title":"二氯-(1,2-苯基-烯二胺-κ 2n,N′)铂的晶体结构(ⅱ)","authors":"Yosuke Konno, Nobuyuki Matsushita","doi":"10.1107/S2056989017008477","DOIUrl":null,"url":null,"abstract":"<p><p>The Pt<sup>II</sup> atom in the title compound, [PtCl<sub>2</sub>{(C<sub>6</sub>H<sub>4</sub>)(NH<sub>2</sub>)<sub>2</sub>}], lies on a twofold rotation axis and has a slightly distorted square-planar coordination environment defined by two N atoms of an 1,2-phenyl-enedi-amine ligand and two Cl<sup>-</sup> ions. In the crystal, the planar complex mol-ecules are stacked parallel to the <i>c</i> axis, resulting in a columnar structure. In a column, an infinite almost straight Pt⋯Pt chain is formed, suggesting weak metal-metal inter-actions [Pt⋯Pt = 3.3475 (8) Å]. The crystal packing is stabilized by a three-dimensional N-H⋯Cl hydrogen-bonding network between the amino groups and the Cl ligands of adjacent mol-ecules.</p>","PeriodicalId":7015,"journal":{"name":"Acta Crystallographica Section E Crystallographic Communications","volume":" ","pages":"1009-1012"},"PeriodicalIF":0.0000,"publicationDate":"2017-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5499279/pdf/","citationCount":"0","resultStr":"{\"title\":\"Crystal structure of di-chlorido-(1,2-phenyl-enedi-amine-κ<sup>2</sup><i>N</i>,<i>N</i>')platinum(II).\",\"authors\":\"Yosuke Konno, Nobuyuki Matsushita\",\"doi\":\"10.1107/S2056989017008477\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>The Pt<sup>II</sup> atom in the title compound, [PtCl<sub>2</sub>{(C<sub>6</sub>H<sub>4</sub>)(NH<sub>2</sub>)<sub>2</sub>}], lies on a twofold rotation axis and has a slightly distorted square-planar coordination environment defined by two N atoms of an 1,2-phenyl-enedi-amine ligand and two Cl<sup>-</sup> ions. In the crystal, the planar complex mol-ecules are stacked parallel to the <i>c</i> axis, resulting in a columnar structure. In a column, an infinite almost straight Pt⋯Pt chain is formed, suggesting weak metal-metal inter-actions [Pt⋯Pt = 3.3475 (8) Å]. The crystal packing is stabilized by a three-dimensional N-H⋯Cl hydrogen-bonding network between the amino groups and the Cl ligands of adjacent mol-ecules.</p>\",\"PeriodicalId\":7015,\"journal\":{\"name\":\"Acta Crystallographica Section E Crystallographic Communications\",\"volume\":\" \",\"pages\":\"1009-1012\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2017-06-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5499279/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Acta Crystallographica Section E Crystallographic Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1107/S2056989017008477\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2017/7/1 0:00:00\",\"PubModel\":\"eCollection\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Acta Crystallographica Section E Crystallographic Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1107/S2056989017008477","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2017/7/1 0:00:00","PubModel":"eCollection","JCR":"","JCRName":"","Score":null,"Total":0}
Crystal structure of di-chlorido-(1,2-phenyl-enedi-amine-κ2N,N')platinum(II).
The PtII atom in the title compound, [PtCl2{(C6H4)(NH2)2}], lies on a twofold rotation axis and has a slightly distorted square-planar coordination environment defined by two N atoms of an 1,2-phenyl-enedi-amine ligand and two Cl- ions. In the crystal, the planar complex mol-ecules are stacked parallel to the c axis, resulting in a columnar structure. In a column, an infinite almost straight Pt⋯Pt chain is formed, suggesting weak metal-metal inter-actions [Pt⋯Pt = 3.3475 (8) Å]. The crystal packing is stabilized by a three-dimensional N-H⋯Cl hydrogen-bonding network between the amino groups and the Cl ligands of adjacent mol-ecules.
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