{"title":"A波段激发CH3I的吸收、磁圆二色性和共振拉曼光谱联合分析","authors":"Bruce R. Johnson, James L. Kinsey","doi":"10.1021/jp9611030","DOIUrl":null,"url":null,"abstract":"<p >The broad structureless A band of CH<sub>3</sub>I has long been assigned to three overlapping transitions, although their relative strengths have been a subject of controversy. A new component analysis is made utilizing a simple dynamical model to rationalize the currently available absorption, magnetic circular dichroism, and resonance Raman excitation spectral data. Discrepancies between these and other CH<sub>3</sub>I photolysis experiments are examined. </p>","PeriodicalId":58,"journal":{"name":"The Journal of Physical Chemistry ","volume":"100 49","pages":"18937–18943"},"PeriodicalIF":2.7810,"publicationDate":"1996-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1021/jp9611030","citationCount":"13","resultStr":"{\"title\":\"Joint Analysis of Absorption, Magnetic Circular Dichroism, and Resonance Raman Spectra of CH3I Excited in the A Band\",\"authors\":\"Bruce R. Johnson, James L. Kinsey\",\"doi\":\"10.1021/jp9611030\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >The broad structureless A band of CH<sub>3</sub>I has long been assigned to three overlapping transitions, although their relative strengths have been a subject of controversy. A new component analysis is made utilizing a simple dynamical model to rationalize the currently available absorption, magnetic circular dichroism, and resonance Raman excitation spectral data. Discrepancies between these and other CH<sub>3</sub>I photolysis experiments are examined. </p>\",\"PeriodicalId\":58,\"journal\":{\"name\":\"The Journal of Physical Chemistry \",\"volume\":\"100 49\",\"pages\":\"18937–18943\"},\"PeriodicalIF\":2.7810,\"publicationDate\":\"1996-12-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1021/jp9611030\",\"citationCount\":\"13\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"The Journal of Physical Chemistry \",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/jp9611030\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Journal of Physical Chemistry ","FirstCategoryId":"1","ListUrlMain":"https://pubs.acs.org/doi/10.1021/jp9611030","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Joint Analysis of Absorption, Magnetic Circular Dichroism, and Resonance Raman Spectra of CH3I Excited in the A Band
The broad structureless A band of CH3I has long been assigned to three overlapping transitions, although their relative strengths have been a subject of controversy. A new component analysis is made utilizing a simple dynamical model to rationalize the currently available absorption, magnetic circular dichroism, and resonance Raman excitation spectral data. Discrepancies between these and other CH3I photolysis experiments are examined.
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