铝-硅酸盐体系中等级结构的循环生长。

Journal of systems chemistry Pub Date : 2015-01-01 Epub Date: 2015-03-06 DOI:10.1186/s13322-015-0007-9
Agnieszka Dyonizy, Vitaliy Kaminker, Joanna Wieckowska, Tomasz Krzywicki, Jim Pantaleone, Piotr Nowak, Jerzy Maselko
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引用次数: 2

摘要

背景:利用环境提供的材料,生物结构从种子自发生长。这些结构是分层的,每一层的“构建块”都是由较低一层的“构建块”构建的。理解和建模发生在许多层次上的过程,然后构建它们,是一项困难的任务。然而,对这一主题的兴趣正在增长。现在有可能研究简单的双组分化学体系中层次结构的自发生长。结果:硅酸铝体系被观察到生长成近似圆锥形的结构。这些结构由多个较小的锥体组成,具有几个层次的复杂性。在最高层次上,该系统类似于一个大都市,有一个水平的资源分配网络连接垂直的锥形结构。这些锥体是由许多较小的锥体组成的,它们连接在一起形成一个具有不同寻常行为的整体。观察到生长在垂直和水平方向之间周期性地转换。结论:观察到在培养皿中生长的结构与其他分层系统(如生物有机体或城市)有许多相似之处。这个系统可以提供一个简单的模型系统来寻找控制复杂层次结构增长的普遍规律。图解摘要化学结构的侧视图,由许多垂直的锥体构成一个化学大都市。最高的建筑有17厘米高。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Cyclic growth of hierarchical structures in the aluminum-silicate system.

Cyclic growth of hierarchical structures in the aluminum-silicate system.

Cyclic growth of hierarchical structures in the aluminum-silicate system.

Cyclic growth of hierarchical structures in the aluminum-silicate system.

Background: Biological structures grow spontaneously from a seed, using materials supplied by the environment. These structures are hierarchical, with the 'building blocks' on each level constructed from those on the lower level. To understand and model the processes that occur on many levels, and later construct them, is a difficult task. However interest in this subject is growing. It is now possible to study the spontaneous growth of hierarchical structures in simple, two component chemical systems.

Results: Aluminum-silicate systems have been observed to grow into structures that are approximately conical. These structures are composed of multiple smaller cones with several hierarchical levels of complexity. On the highest level the system resembles a metropolis, with a horizontal resource distribution network connecting vertical, conical structures. The cones are made from many smaller cones that are connected together forming a whole with unusual behavior. The growth is observed to switch periodically between the vertical and horizontal directions.

Conclusion: A structure grown in a dish is observed to have many similarities to other hierarchical systems such as biological organisms or cities. This system may provide a simple model system to search for universal laws governing the growth of complex hierarchical structures. Graphical AbstractSide view of the chemical structure made from many vertical cones to form a chemical metropolis. The tallest structure is 17 cm high.

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