八水合物氯化锡(IV)的晶体结构。

IF 0.9

Acta crystallographica. Section E, Structure reports online Pub Date : 2014-11-12 eCollection Date: 2014-12-01 DOI:10.1107/S1600536814024271

Erik Hennings, Horst Schmidt, Wolfgang Voigt

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引用次数: 2

摘要

标题化合物[SnCl4(H2O)2]·6H2O根据固液相图在低温下结晶。它是由SnCl4(H2O)2八面体单元(点群对称2)和晶格水分子组成的。在晶体结构中形成了复杂分子和晶格水分子之间的O- h⋯O和O- h⋯Cl氢键的复杂三维网络。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Crystal structure of tin(IV) chloride octa-hydrate.

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Crystal structure of tin(IV) chloride octa-hydrate.

The title compound, [SnCl4(H2O)2]·6H2O, was crystallized according to the solid-liquid phase diagram at lower temperatures. It is built-up of SnCl4(H2O)2 octa-hedral units (point group symmetry 2) and lattice water mol-ecules. An intricate three-dimensional network of O-H⋯O and O-H⋯Cl hydrogen bonds between the complex molecules and the lattice water molecules is formed in the crystal structure.

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来源期刊

Acta crystallographica. Section E, Structure reports online 化学-晶体学

自引率

33.30%

发文量

审稿时长

1.3 months

期刊介绍： Acta Crystallographica Section E: Structure Reports Online is the IUCr highly popular open-access structural journal. It provides a simple and easily accessible publication mechanism for the growing number of inorganic, metal-organic and organic crystal structure determinations. The electronic submission, validation, refereeing and publication facilities of the journal ensure very rapid and high-quality publication, whilst key indicators and validation reports provide measures of structural reliability. In 2009, the journal published over 4000 structures. The average publication time is less than one month.