三水合高氯酸锡的晶体结构。

IF 0.9

Acta crystallographica. Section E, Structure reports online Pub Date : 2014-11-12 eCollection Date: 2014-12-01 DOI:10.1107/S1600536814024283

Erik Hennings, Horst Schmidt, Martin Köhler, Wolfgang Voigt

引用次数: 5

摘要

以六水合高氯酸铜(II)与金属锡在高氯酸中氧化还原反应合成了标题化合物[Sn(H2O)3](ClO4)2。三角锥体[Sn(H2O)3](2+)阳离子和四面体高氯酸盐阴离子均位于晶体三轴上。在晶体中，阳离子通过O- h⋯O氢键与阴离子相连，产生(001)片。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Crystal structure of tin(II) perchlorate trihydrate.

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Crystal structure of tin(II) perchlorate trihydrate.

The title compound, [Sn(H2O)3](ClO4)2, was synthesized by the redox reaction of copper(II) perchlorate hexa-hydrate and metallic tin in perchloric acid. Both the trigonal-pyramidal [Sn(H2O)3](2+) cations and tetra-hedral perchlorate anions lie on crystallographic threefold axes. In the crystal, the cations are linked to the anions by O-H⋯O hydrogen bonds, generating (001) sheets.

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来源期刊

Acta crystallographica. Section E, Structure reports online 化学-晶体学

自引率

33.30%

发文量

审稿时长

1.3 months

期刊介绍： Acta Crystallographica Section E: Structure Reports Online is the IUCr highly popular open-access structural journal. It provides a simple and easily accessible publication mechanism for the growing number of inorganic, metal-organic and organic crystal structure determinations. The electronic submission, validation, refereeing and publication facilities of the journal ensure very rapid and high-quality publication, whilst key indicators and validation reports provide measures of structural reliability. In 2009, the journal published over 4000 structures. The average publication time is less than one month.