水晶的学院——3——[3,5-bis (2,6-di-methyl-phen-yl) -1,2-phenyl-ene]达到华(2,6,2 " 6 " -tetra-methyl-1,1: 3 (" 1 " -ter-phen-yl-5 -yl) imidazol-2-yl-idene chlorido……-(η(6)-p-cymene钌(II) benzene disolvate .

IF 0.9

Acta crystallographica. Section E, Structure reports online Pub Date : 2014-11-08 eCollection Date: 2014-12-01 DOI:10.1107/S160053681402399X

Shohei Sase, Yuriko Ikehara, Kei Goto

{"title":"水晶的学院——3——[3,5-bis (2,6-di-methyl-phen-yl) -1,2-phenyl-ene]达到华(2,6,2 \" 6 \" -tetra-methyl-1,1: 3 (\" 1 \" -ter-phen-yl-5 -yl) imidazol-2-yl-idene chlorido……-(η(6)-p-cymene钌(II) benzene disolvate .","authors":"Shohei Sase, Yuriko Ikehara, Kei Goto","doi":"10.1107/S160053681402399X","DOIUrl":null,"url":null,"abstract":"The title compound, [Ru(C47H43N2)Cl(C10H14)]·2C6H6, crystallized with two independent mol-ecules of benzene. One of the N-aryl moieties of the N-heterocyclic carbene (NHC) ligand underwent cyclo-metallation to form a five-membered ruthenacycle. The complex has a three-legged piano-stool structure with two C atoms incorporated in the five-membered ruthenacycle and a Cl atom as legs. The ruthenacycle is essentially coplanar with the imidazole ring of the NHC ligand, making a dihedral angle of 0.85 (8)°. ","PeriodicalId":7117,"journal":{"name":"Acta crystallographica. Section E, Structure reports online","volume":null,"pages":null},"PeriodicalIF":0.9000,"publicationDate":"2014-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1107/S160053681402399X","citationCount":"0","resultStr":"{\"title\":\"Crystal structure of {3-[3,5-bis-(2,6-di-methyl-phen-yl)-1,2-phenyl-ene]-1-(2,6,2'',6''-tetra-methyl-1,1':3',1''-ter-phen-yl-5'-yl)imidazol-2-yl-idene}chlorido-(η(6)-p-cymene)ruthenium(II) benzene disolvate.\",\"authors\":\"Shohei Sase, Yuriko Ikehara, Kei Goto\",\"doi\":\"10.1107/S160053681402399X\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The title compound, [Ru(C47H43N2)Cl(C10H14)]·2C6H6, crystallized with two independent mol-ecules of benzene. One of the N-aryl moieties of the N-heterocyclic carbene (NHC) ligand underwent cyclo-metallation to form a five-membered ruthenacycle. The complex has a three-legged piano-stool structure with two C atoms incorporated in the five-membered ruthenacycle and a Cl atom as legs. The ruthenacycle is essentially coplanar with the imidazole ring of the NHC ligand, making a dihedral angle of 0.85 (8)°. \",\"PeriodicalId\":7117,\"journal\":{\"name\":\"Acta crystallographica. Section E, Structure reports online\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.9000,\"publicationDate\":\"2014-11-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1107/S160053681402399X\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Acta crystallographica. Section E, Structure reports online\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1107/S160053681402399X\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2014/12/1 0:00:00\",\"PubModel\":\"eCollection\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Acta crystallographica. Section E, Structure reports online","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1107/S160053681402399X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2014/12/1 0:00:00","PubModel":"eCollection","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 0

摘要

标题化合物[Ru(C47H43N2)Cl(C10H14)]·2C6H6与两个独立的苯分子结晶。n -杂环碳(NHC)配体的一个n -芳基部分经过环金属化形成一个五元钌环。该复合物具有三脚钢琴凳结构，其中两个C原子合并在五元钌环中，一个Cl原子作为腿。钌环与NHC配体的咪唑环基本共面，形成0.85(8)°的二面角。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Crystal structure of {3-[3,5-bis-(2,6-di-methyl-phen-yl)-1,2-phenyl-ene]-1-(2,6,2'',6''-tetra-methyl-1,1':3',1''-ter-phen-yl-5'-yl)imidazol-2-yl-idene}chlorido-(η(6)-p-cymene)ruthenium(II) benzene disolvate.

查看原文本刊更多论文

The title compound, [Ru(C47H43N2)Cl(C10H14)]·2C6H6, crystallized with two independent mol-ecules of benzene. One of the N-aryl moieties of the N-heterocyclic carbene (NHC) ligand underwent cyclo-metallation to form a five-membered ruthenacycle. The complex has a three-legged piano-stool structure with two C atoms incorporated in the five-membered ruthenacycle and a Cl atom as legs. The ruthenacycle is essentially coplanar with the imidazole ring of the NHC ligand, making a dihedral angle of 0.85 (8)°.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Acta crystallographica. Section E, Structure reports online 化学-晶体学

自引率

33.30%

发文量

审稿时长

1.3 months

期刊介绍： Acta Crystallographica Section E: Structure Reports Online is the IUCr highly popular open-access structural journal. It provides a simple and easily accessible publication mechanism for the growing number of inorganic, metal-organic and organic crystal structure determinations. The electronic submission, validation, refereeing and publication facilities of the journal ensure very rapid and high-quality publication, whilst key indicators and validation reports provide measures of structural reliability. In 2009, the journal published over 4000 structures. The average publication time is less than one month.