双-{2,4-二叔丁基-6-[(异丙基-亚氨基)-甲基]苯酚-κ(2) N,O}锌二氯甲烷单溶剂化物的晶体结构

IF 0.9

Acta crystallographica. Section E, Structure reports online Pub Date : 2014-11-05 eCollection Date: 2014-12-01 DOI:10.1107/S1600536814022636

Yuan-Zeng Hao

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引用次数: 0

摘要

在标题化合物[Zn(C18H28NO)2]·CH2Cl2中，Zn(II)原子被两个晶体独立的水杨基醛亚胺配体N, o螯合，形成一个扭曲的四面体配位球。两个金属循环平面之间的二面角为88.69(6)°。观察到分子内非经典C-H⋯O氢键相互作用。在晶体中，复杂分子沿着a轴堆叠成柱状。二氯甲烷溶剂分子位于这种排列的空隙中。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Crystal structure of bis-{2,4-di-tert-butyl-6-[(iso-propyl-imino)-meth-yl]phenolato-κ(2) N,O}zinc di-chloro-methane mono-solvate.

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Crystal structure of bis-{2,4-di-tert-butyl-6-[(iso-propyl-imino)-meth-yl]phenolato-κ(2) N,O}zinc di-chloro-methane mono-solvate.

In the title compound, [Zn(C18H28NO)2]·CH2Cl2, the Zn(II) atom is N,O-chelated by two crystallographically independent salicyl-aldehyde imine ligands, leading to a distorted tetra-hedral coordination sphere. The dihedral angle between the planes of the two metallacycles is 88.69 (6)°. Intra-molecular non-classical C-H⋯O hydrogen-bonding inter-actions are observed. In the crystal, the complex mol-ecules stack into columns along the a axis. Di-chloro-methane solvent mol-ecules are situated in the voids of this arrangement.

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来源期刊

Acta crystallographica. Section E, Structure reports online 化学-晶体学

自引率

33.30%

发文量

审稿时长

1.3 months

期刊介绍： Acta Crystallographica Section E: Structure Reports Online is the IUCr highly popular open-access structural journal. It provides a simple and easily accessible publication mechanism for the growing number of inorganic, metal-organic and organic crystal structure determinations. The electronic submission, validation, refereeing and publication facilities of the journal ensure very rapid and high-quality publication, whilst key indicators and validation reports provide measures of structural reliability. In 2009, the journal published over 4000 structures. The average publication time is less than one month.