catena-poly[[(3-叔丁基吡啶-κN)(4-叔丁基吡啶-κN)镉]-di-μ-硫代氰基-κ(2) N:S;κ(2) S:N]的晶体结构。

IF 0.9

Acta crystallographica. Section E, Structure reports online Pub Date : 2014-11-19 eCollection Date: 2014-12-01 DOI:10.1107/S1600536814024647

Julia Werner, Thorben Reinert, Inke Jess, Christian Näther

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引用次数: 0

摘要

在标题化合物[Cd(NCS)2(C9H13N)2] n的晶体结构中，Cd(II)阳离子被1个3-叔丁基吡啶配体、1个4-叔丁基吡啶配体和2对平移相等的μ-1,3桥接硫氰酸酯配体配位在一般位置上，呈轻微畸变的八面体结构。这些μ-1,3桥接的硫代氰阴离子桥接Cd(II)阳离子，形成平行于b轴传播的链。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Crystal structure of catena-poly[[(3-tert-butyl-pyridine-κN)(4-tert-butyl-pyridine-κN)cadmium]-di-μ-thio-cyanato-κ(2) N:S;κ(2) S:N].

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Crystal structure of catena-poly[[(3-tert-butyl-pyridine-κN)(4-tert-butyl-pyridine-κN)cadmium]-di-μ-thio-cyanato-κ(2) N:S;κ(2) S:N].

In the crystal structure of the title compound, [Cd(NCS)2(C9H13N)2] n , the Cd(II) cations are coordinated in a slightly distorted octa-hedral geometry by one 3-tert-butyl-pyridine ligand, one 4-tert-butyl-pyridine ligand and two pairs of translationally-equivalent μ-1,3-bridging thio-cyanate ligands, all of which are in general positions. These μ-1,3-bridging thio-cyante anions bridge the Cd(II) cations, forming chains that propagate parallel to the b axis.

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来源期刊

Acta crystallographica. Section E, Structure reports online 化学-晶体学

自引率

33.30%

发文量

审稿时长

1.3 months

期刊介绍： Acta Crystallographica Section E: Structure Reports Online is the IUCr highly popular open-access structural journal. It provides a simple and easily accessible publication mechanism for the growing number of inorganic, metal-organic and organic crystal structure determinations. The electronic submission, validation, refereeing and publication facilities of the journal ensure very rapid and high-quality publication, whilst key indicators and validation reports provide measures of structural reliability. In 2009, the journal published over 4000 structures. The average publication time is less than one month.