甲氰菊酯的晶体结构。

IF 0.9

Acta crystallographica. Section E, Structure reports online Pub Date : 2014-11-19 eCollection Date: 2014-12-01 DOI:10.1107/S160053681402474X

Gihaeng Kang, Youngeun Jeon, Sangjin Lee, Tae Ho Kim

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引用次数: 2

摘要

标题化合物[系统名称:氰-(3-苯基-氧基-苯基)甲基2,2,3,3-四甲基-环丙烷-羧酸盐]C22H23NO3为拟除虫菊酯杀虫剂，环丙烷环平面与羧酸基平面之间的二面角为88.25(11)°。苯氧苄基中苯环与苯基环之间的二面角为82.99(4)°。在晶体中，C-H⋯N氢键和弱C-H⋯π相互作用连接相邻分子，沿着b轴方向形成环链。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Crystal structure of fenpropathrin.

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Crystal structure of fenpropathrin.

In the title compound [systematic name: cyano-(3-phen-oxy-phen-yl)methyl 2,2,3,3-tetra-methyl-cyclo-propane-carboxyl-ate], C22H23NO3, which is the pyrethroid insecticide fenpropathrin, the dihedral angle between the cyclo-propane ring plane and the carboxyl-ate group plane is 88.25 (11)°. The dihedral angle between the benzene and phenyl rings in the phen-oxy-benzyl group is 82.99 (4)°. In the crystal, C-H⋯N hydrogen bonds and weak C-H⋯π inter-actions link adjacent mol-ecules, forming loop chains along the b-axis direction.

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来源期刊

Acta crystallographica. Section E, Structure reports online 化学-晶体学

自引率

33.30%

发文量

审稿时长

1.3 months

期刊介绍： Acta Crystallographica Section E: Structure Reports Online is the IUCr highly popular open-access structural journal. It provides a simple and easily accessible publication mechanism for the growing number of inorganic, metal-organic and organic crystal structure determinations. The electronic submission, validation, refereeing and publication facilities of the journal ensure very rapid and high-quality publication, whilst key indicators and validation reports provide measures of structural reliability. In 2009, the journal published over 4000 structures. The average publication time is less than one month.