（OC-6-13）-二氟氧基二（丙-2-醇）（丙-2-羟基）钒（V）。

IF 0.8 4区化学

Acta crystallographica. Section C, Crystal structure communications Pub Date : 2013-12-15 Epub Date: 2013-11-08 DOI:10.1107/S0108270113029776

Julia Kohl, Dennis Wiedemann

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引用次数: 1

摘要

以丙二醇为溶剂，氟化氢水溶液在[V(V)O(OiPr)3]处交换配体合成了畸变八面体标题配合物[V(V)(C3H7O)(c3h80)2F2O]，并在238 K下由(D)氯仿结晶。晶体结构测定表明，在不对称单元中存在两个c1对称部分，通过氢键沿[100]形成无限链。该化合物提供了第一个含有[VF2O(OiPr)]基序的晶体结构。

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(OC-6-13)-difluoridooxidobis(propan-2-ol)(propan-2-olato)vanadium(V).

The distorted octahedral title complex, [V(V)(C3H7O)(C3H8O)2F2O], was synthesized via ligand exchange at [V(V)O(OiPr)3] with aqueous hydrogen fluoride in propan-2-ol and crystallized from (D)chloroform at 238 K after a few weeks. Crystal structure determination shows two C1-symmetric moieties to be present in the asymmetric unit, forming infinite chains along [100] via hydrogen bonds. The compound provides the first crystal structure containing the [VF2O(OiPr)] motif.

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来源期刊

Acta crystallographica. Section C, Crystal structure communications 化学-晶体学

自引率

12.50%

发文量

审稿时长

1 months

期刊介绍： Acta Crystallographica Section C: Structural Chemistry is continuing its transition to a journal that publishes exciting science with structural content, in particular, important results relating to the chemical sciences. Section C is the journal of choice for the rapid publication of articles that highlight interesting research facilitated by the determination, calculation or analysis of structures of any type, other than macromolecular structures. Articles that emphasize the science and the outcomes that were enabled by the study are particularly welcomed. Authors are encouraged to include mainstream science in their papers, thereby producing manuscripts that are substantial scientific well-rounded contributions that appeal to a broad community of readers and increase the profile of the authors.