4,4'-{二氮二基双[(1,4-苯基)双(羰基氧基)]}双(2,2,6,6-四甲基哌啶基氧基):首次用粉末数据测定氮氧化物自由基的晶体结构。

IF 0.8 4区化学

Acta crystallographica. Section C, Crystal structure communications Pub Date : 2013-12-15 Epub Date: 2013-11-08 DOI:10.1107/S0108270113029211

Sándor L Bekö, Silke D Thoms, Martin U Schmidt

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引用次数: 2

摘要

标题化合物C32H42N4O6是一种用于脉冲电子-电子双共振(PELDOR)光谱的新型氮氧化物自由基。其晶体结构由实验室x射线粉末衍射数据确定。晶体结构中分子间的吸引力主要是色散性的。没有观察到氮氧化物自由基的特殊相互作用。

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4,4'-{Diazenediylbis[(1,4-phenylene)bis(carbonyloxy)]}bis(2,2,6,6-tetramethylpiperidinyloxidanyl): the first crystal structure determination from powder data of a nitroxide radical.

The title compound, C32H42N4O6, is a novel nitroxide radical used for pulsed electron-electron double resonance (PELDOR) spectroscopy. Its crystal structure was determined from laboratory X-ray powder diffraction data. The attractive forces between the molecules in the crystal structure are mainly of dispersive nature. A special interaction of the nitroxide radicals was not observed.

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来源期刊

Acta crystallographica. Section C, Crystal structure communications 化学-晶体学

自引率

12.50%

发文量

审稿时长

1 months

期刊介绍： Acta Crystallographica Section C: Structural Chemistry is continuing its transition to a journal that publishes exciting science with structural content, in particular, important results relating to the chemical sciences. Section C is the journal of choice for the rapid publication of articles that highlight interesting research facilitated by the determination, calculation or analysis of structures of any type, other than macromolecular structures. Articles that emphasize the science and the outcomes that were enabled by the study are particularly welcomed. Authors are encouraged to include mainstream science in their papers, thereby producing manuscripts that are substantial scientific well-rounded contributions that appeal to a broad community of readers and increase the profile of the authors.