异金属镉银配合物顺式-双氰银(I)-κN]双(5,5'-二甲基-2,2'-联吡啶基-κ(2)N,N')镉(II)一水化合物。

IF 0.8 4区化学

Acta crystallographica. Section C, Crystal structure communications Pub Date : 2013-10-01 Epub Date: 2013-09-28 DOI:10.1107/S0108270113025201

Jureepan Piromchom, Nanthawat Wannarit, Chaveng Pakawatchai, Sujittra Youngme

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引用次数: 3

摘要

在标题配合物[Ag2Cd(CN)4(C12H12N2)2]·H2O或顺式-[Cd{Ag(CN)2}2(5,5'-dmbpy)2]·H2O中，其中5,5'-dmbpy为5,5'-二甲基-2,2'-联吡啶基，不对称单元由离散的中性单元[Cd{Ag(CN)2}2(5,5'-dmbpy)2]和溶剂水分子组成。Cd(II)阳离子由两个双齿螯合5,5'-dmbpy配体和两个单齿[Ag(I)(CN)2](-)阴离子配位，它们以顺式排列在Cd(II)阳离子周围，形成CdN6的八面体结构。分子间氢键结合Ag(I)···Ag(I)和π-π相互作用稳定了整体结构，形成了三维超分子网络。

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The heterometallic cadmium-silver complex cis-bis[dicyanidoargentato(I)-κN]bis(5,5'-dimethyl-2,2'-bipyridyl-κ(2)N,N')cadmium(II) monohydrate.

In the title complex, [Ag2Cd(CN)4(C12H12N2)2]·H2O or cis-[Cd{Ag(CN)2}2(5,5'-dmbpy)2]·H2O, where 5,5'-dmbpy is 5,5'-dimethyl-2,2'-bipyridyl, the asymmetric unit consists of a discrete neutral [Cd{Ag(CN)2}2(5,5'-dmbpy)2] unit and a solvent water molecule. The Cd(II) cation is coordinated by two bidentate chelate 5,5'-dmbpy ligands and two monodentate [Ag(I)(CN)2](-) anions, which are in a cis arrangement around the Cd(II) cation, leading to an octahedral CdN6 geometry. The overall structure is stabilized by a combination of intermolecular hydrogen bonding, and Ag(I)···Ag(I) and π-π interactions, forming a three-dimensional supramolecular network.

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来源期刊

Acta crystallographica. Section C, Crystal structure communications 化学-晶体学

自引率

12.50%

发文量

审稿时长

1 months

期刊介绍： Acta Crystallographica Section C: Structural Chemistry is continuing its transition to a journal that publishes exciting science with structural content, in particular, important results relating to the chemical sciences. Section C is the journal of choice for the rapid publication of articles that highlight interesting research facilitated by the determination, calculation or analysis of structures of any type, other than macromolecular structures. Articles that emphasize the science and the outcomes that were enabled by the study are particularly welcomed. Authors are encouraged to include mainstream science in their papers, thereby producing manuscripts that are substantial scientific well-rounded contributions that appeal to a broad community of readers and increase the profile of the authors.