[从热带海星Asteropsis carinifera中提取的三种新的多羟基类固醇]。

Bioorganicheskaia khimiia Pub Date : 2010-11-01
T V Maliarenko, A A Kicha, N V Ivanchina, A I Kalinovskiĭ, P S Dmitrenok, A V Smirnov
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引用次数: 0

摘要

从越南沿海采集的热带海星Asteropsis carinifera中分离到13种甾体化合物,包括3种新的多羟基类固醇(24R,25S)-24-甲基-5α-胆甾-3β,6α,8,15β,16β, 16β,26-己醇,(22E,24R,25S)-24-甲基-5α-胆甾-22-烯-3β,6α,8,15β,16β,26-七醇和(22E,24R,25S)-24-甲基-5α-胆甾-22-烯-3β,4β,6α,8,15β,16β,26-七醇。用波谱方法(主要是二维核磁共振和esi质谱)对新化合物的结构进行了鉴定。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
[Three new polyhydroxysteroids from the tropical starfish Asteropsis carinifera].

Thirteen steroidal compounds including three new polyhydroxysteroids, (24R,25S)-24-methyl-5α-cholestane-3β,6α,8,15β,16β,26-hexaol, (22E,24R,25S)-24-methyl-5α-cholest-22-ene-3β,6α,8,15β,16β,26-hexaol and (22E,24R,25S)-24-methyl-5α-cholest-22-ene-3β,4β,6α,8,15β,16β,26-heptaol, have been isolated along with the previously known ten polyhydroxysteroids from the tropical starfish Asteropsis carinifera collected near the coast of Vietnam. The structures of new compounds were elucidated by spectroscopic methods (mainly 2D NMR and ESI-mass-spectrometry).

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