{"title":"[ECD气相色谱仪测定食品中总溴]。","authors":"R Matsuda, K Sasaki, Y Saito","doi":"","DOIUrl":null,"url":null,"abstract":"<p><p>A determination method for total bromine that presents in various chemical forms in foods by gas chromatograph with ECD was investigated. Food samples were ashed with KOH at 600 degrees C for 2h and the residue was dissolved in water and filtered. The filtrate was acidified with sulfuric acid, and potassium permanganate solution was added to the solution. The liberated bromine was reacted with cyclopentanone and the product was extracted with hexane and quantified by gas chromatograph with ECD. Recovery of bromine by this method was more than 80% and the detection limit was lower than that of the conventional method. The total bromide in the samples prepared for the total diet study program was quantified by this method and the total intake of bromine was estimated. The total intake of bromine was 8-12 mg and about 20% of ADI (1 mg/kg/day).</p>","PeriodicalId":11656,"journal":{"name":"Eisei Shikenjo hokoku. Bulletin of National Institute of Hygienic Sciences","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1994-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"[Determination of total bromine in foods by ECD gas chromatograph].\",\"authors\":\"R Matsuda, K Sasaki, Y Saito\",\"doi\":\"\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>A determination method for total bromine that presents in various chemical forms in foods by gas chromatograph with ECD was investigated. Food samples were ashed with KOH at 600 degrees C for 2h and the residue was dissolved in water and filtered. The filtrate was acidified with sulfuric acid, and potassium permanganate solution was added to the solution. The liberated bromine was reacted with cyclopentanone and the product was extracted with hexane and quantified by gas chromatograph with ECD. Recovery of bromine by this method was more than 80% and the detection limit was lower than that of the conventional method. The total bromide in the samples prepared for the total diet study program was quantified by this method and the total intake of bromine was estimated. The total intake of bromine was 8-12 mg and about 20% of ADI (1 mg/kg/day).</p>\",\"PeriodicalId\":11656,\"journal\":{\"name\":\"Eisei Shikenjo hokoku. Bulletin of National Institute of Hygienic Sciences\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1994-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Eisei Shikenjo hokoku. Bulletin of National Institute of Hygienic Sciences\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Eisei Shikenjo hokoku. Bulletin of National Institute of Hygienic Sciences","FirstCategoryId":"1085","ListUrlMain":"","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
[Determination of total bromine in foods by ECD gas chromatograph].
A determination method for total bromine that presents in various chemical forms in foods by gas chromatograph with ECD was investigated. Food samples were ashed with KOH at 600 degrees C for 2h and the residue was dissolved in water and filtered. The filtrate was acidified with sulfuric acid, and potassium permanganate solution was added to the solution. The liberated bromine was reacted with cyclopentanone and the product was extracted with hexane and quantified by gas chromatograph with ECD. Recovery of bromine by this method was more than 80% and the detection limit was lower than that of the conventional method. The total bromide in the samples prepared for the total diet study program was quantified by this method and the total intake of bromine was estimated. The total intake of bromine was 8-12 mg and about 20% of ADI (1 mg/kg/day).
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