Onema C Adojoh, William Trabal, Favour Adewuyi, Kayode Ayinde, Michael Bellamy, Mohammed J Meziani, Luke Monroe
{"title":"爱荷华州和内布拉斯加-密苏里河漫滩湖泊和池塘微量元素的空间和运动尺度动态。","authors":"Onema C Adojoh, William Trabal, Favour Adewuyi, Kayode Ayinde, Michael Bellamy, Mohammed J Meziani, Luke Monroe","doi":"10.1007/s10653-026-03525-w","DOIUrl":null,"url":null,"abstract":"<p><p>Trace-element contamination in small floodplain water bodies can vary sharply among neighboring catchments, and regional averages may conceal individual hotspots. Water from six lakes and ponds in western Iowa and eastern Nebraska were examined during three site-wide surveys: Summer 2024, Fall 2025, and Spring 2026, yielding 18 site-campaign observations. Eleven trace elements-aluminum (Al), arsenic (As), cadmium (Cd), cobalt (Co), copper (Cu), iron (Fe), manganese (Mn), nickel (Ni), lead (Pb), selenium (Se), and zinc (Zn) were retained after data verification, and concentrations were standardized to µg L<sup>-1</sup>. Site-specific exceedance ratios (ER = C/S) and Heavy Metal Pollution Index (HPI) values were calculated using the study screening benchmarks. Lake Manawa had the highest mean HPI (327.13) and the highest overall mean ER (1.85), driven principally by Co (mean ER = 7.19), Pb (5.16), Mn (1.99), Al (1.94), and Cd (1.49). Among the remaining sites, Pinky's Glen had the highest mean ER (1.57), dominated by Mn (5.31), Al (3.24), and Co (3.15), whereas Steinhart Park showed elevated Mn (5.61), Co (3.05), and Al (2.59). An additive two-factor variance partition indicated that water-body identity accounted for more than 90% of variation in Al, Co, Cu, Fe, Mn, Pb, and Zn during the sampled campaigns. The campaign accounted for 95.8% of As variation and 54.2% of Cd variation. An equal-weight score based on min-max-normalized mean HPI, exceedance frequency, and mean ER ranked Lake Manawa, Pinky's Glen, and Steinhart Park as the three highest priorities for confirmatory monitoring. A recovered physicochemical survey showed the highest mean TDS and EC at Carter Lake (264.67 mg L<sup>-1</sup> and 529.33 µS cm<sup>-1</sup>), water temperatures of 3.03-6.57 °C, and circumneutral mean pH (6.95-7.62). Because the three surveys occurred in different years, temporal comparisons and benchmark exceedances are interpreted as screening-level evidence. The findings support site- and analyte-specific confirmatory monitoring rather than pooled regional assessment.</p>","PeriodicalId":11759,"journal":{"name":"Environmental Geochemistry and Health","volume":"48 16","pages":""},"PeriodicalIF":4.3000,"publicationDate":"2026-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Spatial and campaign-scale dynamics of trace elements in lakes and ponds of the Iowa and Nebraska - Missouri River floodplain.\",\"authors\":\"Onema C Adojoh, William Trabal, Favour Adewuyi, Kayode Ayinde, Michael Bellamy, Mohammed J Meziani, Luke Monroe\",\"doi\":\"10.1007/s10653-026-03525-w\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Trace-element contamination in small floodplain water bodies can vary sharply among neighboring catchments, and regional averages may conceal individual hotspots. Water from six lakes and ponds in western Iowa and eastern Nebraska were examined during three site-wide surveys: Summer 2024, Fall 2025, and Spring 2026, yielding 18 site-campaign observations. Eleven trace elements-aluminum (Al), arsenic (As), cadmium (Cd), cobalt (Co), copper (Cu), iron (Fe), manganese (Mn), nickel (Ni), lead (Pb), selenium (Se), and zinc (Zn) were retained after data verification, and concentrations were standardized to µg L<sup>-1</sup>. Site-specific exceedance ratios (ER = C/S) and Heavy Metal Pollution Index (HPI) values were calculated using the study screening benchmarks. Lake Manawa had the highest mean HPI (327.13) and the highest overall mean ER (1.85), driven principally by Co (mean ER = 7.19), Pb (5.16), Mn (1.99), Al (1.94), and Cd (1.49). Among the remaining sites, Pinky's Glen had the highest mean ER (1.57), dominated by Mn (5.31), Al (3.24), and Co (3.15), whereas Steinhart Park showed elevated Mn (5.61), Co (3.05), and Al (2.59). An additive two-factor variance partition indicated that water-body identity accounted for more than 90% of variation in Al, Co, Cu, Fe, Mn, Pb, and Zn during the sampled campaigns. The campaign accounted for 95.8% of As variation and 54.2% of Cd variation. An equal-weight score based on min-max-normalized mean HPI, exceedance frequency, and mean ER ranked Lake Manawa, Pinky's Glen, and Steinhart Park as the three highest priorities for confirmatory monitoring. A recovered physicochemical survey showed the highest mean TDS and EC at Carter Lake (264.67 mg L<sup>-1</sup> and 529.33 µS cm<sup>-1</sup>), water temperatures of 3.03-6.57 °C, and circumneutral mean pH (6.95-7.62). Because the three surveys occurred in different years, temporal comparisons and benchmark exceedances are interpreted as screening-level evidence. The findings support site- and analyte-specific confirmatory monitoring rather than pooled regional assessment.</p>\",\"PeriodicalId\":11759,\"journal\":{\"name\":\"Environmental Geochemistry and Health\",\"volume\":\"48 16\",\"pages\":\"\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2026-10-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Environmental Geochemistry and Health\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://doi.org/10.1007/s10653-026-03525-w\",\"RegionNum\":3,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENGINEERING, ENVIRONMENTAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Environmental Geochemistry and Health","FirstCategoryId":"93","ListUrlMain":"https://doi.org/10.1007/s10653-026-03525-w","RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENGINEERING, ENVIRONMENTAL","Score":null,"Total":0}
Spatial and campaign-scale dynamics of trace elements in lakes and ponds of the Iowa and Nebraska - Missouri River floodplain.
Trace-element contamination in small floodplain water bodies can vary sharply among neighboring catchments, and regional averages may conceal individual hotspots. Water from six lakes and ponds in western Iowa and eastern Nebraska were examined during three site-wide surveys: Summer 2024, Fall 2025, and Spring 2026, yielding 18 site-campaign observations. Eleven trace elements-aluminum (Al), arsenic (As), cadmium (Cd), cobalt (Co), copper (Cu), iron (Fe), manganese (Mn), nickel (Ni), lead (Pb), selenium (Se), and zinc (Zn) were retained after data verification, and concentrations were standardized to µg L-1. Site-specific exceedance ratios (ER = C/S) and Heavy Metal Pollution Index (HPI) values were calculated using the study screening benchmarks. Lake Manawa had the highest mean HPI (327.13) and the highest overall mean ER (1.85), driven principally by Co (mean ER = 7.19), Pb (5.16), Mn (1.99), Al (1.94), and Cd (1.49). Among the remaining sites, Pinky's Glen had the highest mean ER (1.57), dominated by Mn (5.31), Al (3.24), and Co (3.15), whereas Steinhart Park showed elevated Mn (5.61), Co (3.05), and Al (2.59). An additive two-factor variance partition indicated that water-body identity accounted for more than 90% of variation in Al, Co, Cu, Fe, Mn, Pb, and Zn during the sampled campaigns. The campaign accounted for 95.8% of As variation and 54.2% of Cd variation. An equal-weight score based on min-max-normalized mean HPI, exceedance frequency, and mean ER ranked Lake Manawa, Pinky's Glen, and Steinhart Park as the three highest priorities for confirmatory monitoring. A recovered physicochemical survey showed the highest mean TDS and EC at Carter Lake (264.67 mg L-1 and 529.33 µS cm-1), water temperatures of 3.03-6.57 °C, and circumneutral mean pH (6.95-7.62). Because the three surveys occurred in different years, temporal comparisons and benchmark exceedances are interpreted as screening-level evidence. The findings support site- and analyte-specific confirmatory monitoring rather than pooled regional assessment.
期刊介绍:
Environmental Geochemistry and Health publishes original research papers and review papers across the broad field of environmental geochemistry. Environmental geochemistry and health establishes and explains links between the natural or disturbed chemical composition of the earth’s surface and the health of plants, animals and people.
Beneficial elements regulate or promote enzymatic and hormonal activity whereas other elements may be toxic. Bedrock geochemistry controls the composition of soil and hence that of water and vegetation. Environmental issues, such as pollution, arising from the extraction and use of mineral resources, are discussed. The effects of contaminants introduced into the earth’s geochemical systems are examined. Geochemical surveys of soil, water and plants show how major and trace elements are distributed geographically. Associated epidemiological studies reveal the possibility of causal links between the natural or disturbed geochemical environment and disease. Experimental research illuminates the nature or consequences of natural or disturbed geochemical processes.
The journal particularly welcomes novel research linking environmental geochemistry and health issues on such topics as: heavy metals (including mercury), persistent organic pollutants (POPs), and mixed chemicals emitted through human activities, such as uncontrolled recycling of electronic-waste; waste recycling; surface-atmospheric interaction processes (natural and anthropogenic emissions, vertical transport, deposition, and physical-chemical interaction) of gases and aerosols; phytoremediation/restoration of contaminated sites; food contamination and safety; environmental effects of medicines; effects and toxicity of mixed pollutants; speciation of heavy metals/metalloids; effects of mining; disturbed geochemistry from human behavior, natural or man-made hazards; particle and nanoparticle toxicology; risk and the vulnerability of populations, etc.