城市臭氧不达标:美国西部山间地区相互关联的挑战

IF 2.2
Ellis S Robinson, Chayan Roychoudhury, Yousaf Hameed, Ryan Bares, Tom Moore, Pierre Herckes, Matthew P Fraser, Avelino Arellano, Armin Sorooshian
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引用次数: 0

摘要

尽管人为前体排放持续减少,但在美国西部山间地区的四个大型城市未达标地区(NAAs),臭氧设计值仍高于2015年8小时国家环境空气质量标准:亚利桑那州凤凰城-梅萨;内华达州的拉斯维加斯;犹他州的Wasatch Front;以及科罗拉多州的丹佛地铁/北Front Range。我们综合了最近的实地活动、监管分析和观测约束模型,总结了进展停滞的共同驱动因素和调节臭氧积累的区域特定机制。在这些地区,背景臭氧升高、地形驱动的再循环以及有利于停滞和垂直耦合的气象条件都降低了当地排放控制的有效性。然而,许多重要的因素也因大气的不同而不同:凤凰受到季风调节的光化学和边界层动力学的强烈影响;拉斯维加斯经常受到高空和高空臭氧“地板”富含臭氧层的夹带;瓦萨奇前线受走廊限制、背景浓度升高和多日再循环影响;复杂地形流与空间异质性前驱源相互作用,包括naa内强油气排放。综上所述,每一个案例研究都强调了在协调合作科学的支持下,针对每个空气棚的结构和动力限制制定臭氧管理战略的必要性。结论:Robinson等。城市臭氧不达标:美国西部山间地区相互关联的挑战尽管几十年来人为排放的前体物质不断减少,但美国西部四个主要的山间大都市——凤凰城、拉斯维加斯、盐湖城和丹佛——继续超过2015年的8小时臭氧标准。这种综合确定了导致持续不达标的共同因素和特定因素。背景臭氧升高、野火烟雾、地形驱动的再循环和垂直夹带都极大地限制了局部控制的有效性,尽管不同地区的主要机制不同。对于立法者和监管者来说,这些问题强调了制定区域特定战略、加强垂直分析和特定前体监测的必要性,以及改进可控与运输贡献的归属,以支持技术上站得住的监管决策。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Urban ozone nonattainment: Interconnected challenges in the Intermountain Western U.S.

Despite sustained estimated reductions in anthropogenic precursor emissions, ozone design values remain above the 2015 8-hour National Ambient Air Quality Standard in four large, urban nonattainment areas (NAAs) in the Intermountain Western U.S.: Phoenix-Mesa, Arizona; Las Vegas, Nevada; Wasatch Front, Utah; and Denver Metro/North Front Range, Colorado. We synthesize recent field campaigns, regulatory analyses, and observationally constrained modeling to summarize shared drivers of stalled progress and the region-specific mechanisms that modulate ozone accumulation. Across these areas, elevated background ozone, terrain-driven recirculation, and meteorological conditions favoring stagnation and vertical coupling all reduce the effectiveness of local emission controls. However, many important factors also differ by airshed: Phoenix is strongly influenced by monsoon-modulated photochemistry and boundary-layer dynamics; Las Vegas by frequent entrainment of ozone-rich layers from aloft and a high ozone "floor"; the Wasatch Front by corridor confinement, elevated background concentrations, and multi-day recirculation; and the Front Range by complex terrain flows interacting with spatially heterogeneous precursor sources, including strong within-NAA oil and gas emissions. Together, each of these case studies underscores the need for ozone management strategies tailored to each airshed's structural and dynamical constraints, supported by coordinated collaborative science.Implications: Despite decades of declining anthropogenic precursor emissions, four major Intermountain Western U.S. metropolitan areas (Phoenix, Las Vegas, Salt Lake City, and Denver) continue to exceed the 2015 ozone standard. This synthesis identifies factors, both shared and specific to each airshed, driving persistent nonattainment. Elevated background ozone, wildfire smoke, terrain driven recirculation, and vertical entrainment all limit the effectiveness of local controls, though dominant mechanisms differ by area. For lawmakers and regulators, these findings underscore the need for region specific strategies, better vertical and precursor monitoring, and improved attribution of controllable versus transported ozone to support sound, technically defensible regulatory decisions.

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