基于醇胺溶液的高炉煤气精细脱硫碳捕集剂的配方

IF 3.6 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL
Jian He, Gou Haobo, Geng Liyu, Shu Hao, Yuling Liu, Zhang Lei
{"title":"基于醇胺溶液的高炉煤气精细脱硫碳捕集剂的配方","authors":"Jian He, Gou Haobo, Geng Liyu, Shu Hao, Yuling Liu, Zhang Lei","doi":"10.4491/eer.2024.648","DOIUrl":null,"url":null,"abstract":"The development of deep desulfurization of blast furnace gas combined with carbon capture is the key implementation point of pollution reduction and carbon reduction in the steel industry. Combined with the current situation of immature deep desulfurization technology and urgent demand for carbon capture, a CO2/COS(carbon oxysulfide)/H2S integrated high-efficiency removal formula absorbent was designed and developed. The main conclusions of this paper are as follows: The absorbent system for simultaneous deep removal of CO2, H2S and COS from blast furnace gas was constructed, and the formula absorbent composed of 1.5 mol/L MDEA + 0.5 mol/L MEA + 6% MOR + 4% DBU + 3% DDBAC was obtained. The total sulfur in the purified gas is less than 20 mg/Nm³, with a CO2 capture efficiency greater than 90%, and the regeneration rate of the formulated absorbent is above 80%, exhibiting excellent anti-corrosion and thermal stability performance. This research lays the foundation for the practical implementation of collaborative pollution reduction and carbon reduction in the steel industry. It integrates the achievement of ultra-low emissions and carbon reduction, providing significant environmental and economic benefits, and demonstrates important practical value and research significance.","PeriodicalId":11704,"journal":{"name":"Environmental Engineering Research","volume":"30 5","pages":"240648-0"},"PeriodicalIF":3.6000,"publicationDate":"2025-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"http://www.eeer.org/upload/eer-2024-648.pdf","citationCount":"1","resultStr":"{\"title\":\"Formulated absorbent for fine desulfurization and carbon capture of blast furnace gas based on alcohol amine solution\",\"authors\":\"Jian He, Gou Haobo, Geng Liyu, Shu Hao, Yuling Liu, Zhang Lei\",\"doi\":\"10.4491/eer.2024.648\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The development of deep desulfurization of blast furnace gas combined with carbon capture is the key implementation point of pollution reduction and carbon reduction in the steel industry. Combined with the current situation of immature deep desulfurization technology and urgent demand for carbon capture, a CO2/COS(carbon oxysulfide)/H2S integrated high-efficiency removal formula absorbent was designed and developed. The main conclusions of this paper are as follows: The absorbent system for simultaneous deep removal of CO2, H2S and COS from blast furnace gas was constructed, and the formula absorbent composed of 1.5 mol/L MDEA + 0.5 mol/L MEA + 6% MOR + 4% DBU + 3% DDBAC was obtained. The total sulfur in the purified gas is less than 20 mg/Nm³, with a CO2 capture efficiency greater than 90%, and the regeneration rate of the formulated absorbent is above 80%, exhibiting excellent anti-corrosion and thermal stability performance. This research lays the foundation for the practical implementation of collaborative pollution reduction and carbon reduction in the steel industry. It integrates the achievement of ultra-low emissions and carbon reduction, providing significant environmental and economic benefits, and demonstrates important practical value and research significance.\",\"PeriodicalId\":11704,\"journal\":{\"name\":\"Environmental Engineering Research\",\"volume\":\"30 5\",\"pages\":\"240648-0\"},\"PeriodicalIF\":3.6000,\"publicationDate\":\"2025-02-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"http://www.eeer.org/upload/eer-2024-648.pdf\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Environmental Engineering Research\",\"FirstCategoryId\":\"0\",\"ListUrlMain\":\"https://doi.org/10.4491/eer.2024.648\",\"RegionNum\":4,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENGINEERING, ENVIRONMENTAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Environmental Engineering Research","FirstCategoryId":"0","ListUrlMain":"https://doi.org/10.4491/eer.2024.648","RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENGINEERING, ENVIRONMENTAL","Score":null,"Total":0}
引用次数: 1

摘要

发展高炉煤气深度脱硫与碳捕集相结合,是钢铁工业减少污染、减少碳排放的关键实施点。结合目前深度脱硫技术不成熟的现状和碳捕集的迫切需求,设计并开发了CO2/COS(氧硫化碳)/H2S一体化高效脱除配方吸附剂。本文的主要结论如下:构建了同时深度脱除高炉煤气中CO2、H2S和COS的吸附剂体系,得到了由1.5 mol/L MDEA + 0.5 mol/L MEA + 6% MOR + 4% DBU + 3% DDBAC组成的吸附剂配方。净化后的气体中总硫小于20 mg/Nm³,CO2捕集效率大于90%,配制的吸收剂再生率在80%以上,具有优异的防腐和热稳定性。本研究为钢铁行业协同减污减碳的实际实施奠定了基础。它融合了超低排放和碳减排的成果,提供了显著的环境效益和经济效益,具有重要的实用价值和研究意义。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Formulated absorbent for fine desulfurization and carbon capture of blast furnace gas based on alcohol amine solution
The development of deep desulfurization of blast furnace gas combined with carbon capture is the key implementation point of pollution reduction and carbon reduction in the steel industry. Combined with the current situation of immature deep desulfurization technology and urgent demand for carbon capture, a CO2/COS(carbon oxysulfide)/H2S integrated high-efficiency removal formula absorbent was designed and developed. The main conclusions of this paper are as follows: The absorbent system for simultaneous deep removal of CO2, H2S and COS from blast furnace gas was constructed, and the formula absorbent composed of 1.5 mol/L MDEA + 0.5 mol/L MEA + 6% MOR + 4% DBU + 3% DDBAC was obtained. The total sulfur in the purified gas is less than 20 mg/Nm³, with a CO2 capture efficiency greater than 90%, and the regeneration rate of the formulated absorbent is above 80%, exhibiting excellent anti-corrosion and thermal stability performance. This research lays the foundation for the practical implementation of collaborative pollution reduction and carbon reduction in the steel industry. It integrates the achievement of ultra-low emissions and carbon reduction, providing significant environmental and economic benefits, and demonstrates important practical value and research significance.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Environmental Engineering Research
Environmental Engineering Research Environmental Science-Environmental Engineering
CiteScore
7.50
自引率
5.70%
发文量
80
期刊介绍: The Environmental Engineering Research (EER) is published quarterly by the Korean Society of Environmental Engineers (KSEE). The EER covers a broad spectrum of the science and technology of air, soil, and water management while emphasizing scientific and engineering solutions to environmental issues encountered in industrialization and urbanization. Particularly, interdisciplinary topics and multi-regional/global impacts (including eco-system and human health) of environmental pollution as well as scientific and engineering aspects of novel technologies are considered favorably. The scope of the Journal includes the following areas, but is not limited to: 1. Atmospheric Environment & Climate Change: Global and local climate change, greenhouse gas control, and air quality modeling. 2. Renewable Energy & Waste Management: Energy recovery from waste, incineration, landfill, and green energy. 3. Environmental Biotechnology & Ecology: Nano-biosensor, environmental genomics, bioenergy, and environmental eco-engineering. 4. Physical & Chemical Technology: Membrane technology and advanced oxidation. 5. Environmental System Engineering: Seawater desalination, ICA (instrument, control, and automation), and water reuse. 6. Environmental Health & Toxicology: Micropollutants, hazardous materials, ecotoxicity, and environmental risk assessment.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信
小红书