Jian He, Gou Haobo, Geng Liyu, Shu Hao, Yuling Liu, Zhang Lei
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引用次数: 1
摘要
发展高炉煤气深度脱硫与碳捕集相结合,是钢铁工业减少污染、减少碳排放的关键实施点。结合目前深度脱硫技术不成熟的现状和碳捕集的迫切需求,设计并开发了CO2/COS(氧硫化碳)/H2S一体化高效脱除配方吸附剂。本文的主要结论如下:构建了同时深度脱除高炉煤气中CO2、H2S和COS的吸附剂体系,得到了由1.5 mol/L MDEA + 0.5 mol/L MEA + 6% MOR + 4% DBU + 3% DDBAC组成的吸附剂配方。净化后的气体中总硫小于20 mg/Nm³,CO2捕集效率大于90%,配制的吸收剂再生率在80%以上,具有优异的防腐和热稳定性。本研究为钢铁行业协同减污减碳的实际实施奠定了基础。它融合了超低排放和碳减排的成果,提供了显著的环境效益和经济效益,具有重要的实用价值和研究意义。
Formulated absorbent for fine desulfurization and carbon capture of blast furnace gas based on alcohol amine solution
The development of deep desulfurization of blast furnace gas combined with carbon capture is the key implementation point of pollution reduction and carbon reduction in the steel industry. Combined with the current situation of immature deep desulfurization technology and urgent demand for carbon capture, a CO2/COS(carbon oxysulfide)/H2S integrated high-efficiency removal formula absorbent was designed and developed. The main conclusions of this paper are as follows: The absorbent system for simultaneous deep removal of CO2, H2S and COS from blast furnace gas was constructed, and the formula absorbent composed of 1.5 mol/L MDEA + 0.5 mol/L MEA + 6% MOR + 4% DBU + 3% DDBAC was obtained. The total sulfur in the purified gas is less than 20 mg/Nm³, with a CO2 capture efficiency greater than 90%, and the regeneration rate of the formulated absorbent is above 80%, exhibiting excellent anti-corrosion and thermal stability performance. This research lays the foundation for the practical implementation of collaborative pollution reduction and carbon reduction in the steel industry. It integrates the achievement of ultra-low emissions and carbon reduction, providing significant environmental and economic benefits, and demonstrates important practical value and research significance.
期刊介绍:
The Environmental Engineering Research (EER) is published quarterly by the Korean Society of Environmental Engineers (KSEE). The EER covers a broad spectrum of the science and technology of air, soil, and water management while emphasizing scientific and engineering solutions to environmental issues encountered in industrialization and urbanization. Particularly, interdisciplinary topics and multi-regional/global impacts (including eco-system and human health) of environmental pollution as well as scientific and engineering aspects of novel technologies are considered favorably. The scope of the Journal includes the following areas, but is not limited to:
1. Atmospheric Environment & Climate Change: Global and local climate change, greenhouse gas control, and air quality modeling.
2. Renewable Energy & Waste Management: Energy recovery from waste, incineration, landfill, and green energy.
3. Environmental Biotechnology & Ecology: Nano-biosensor, environmental genomics, bioenergy, and environmental eco-engineering.
4. Physical & Chemical Technology: Membrane technology and advanced oxidation.
5. Environmental System Engineering: Seawater desalination, ICA (instrument, control, and automation), and water reuse.
6. Environmental Health & Toxicology: Micropollutants, hazardous materials, ecotoxicity, and environmental risk assessment.