{"title":"碳含量对FeCrMn1.5AlCuC高熵合金组织和摩擦学性能的影响","authors":"Kai Ma , Li Feng , Yanchun Zhao , Jianjun Liu","doi":"10.1016/j.intermet.2025.109029","DOIUrl":null,"url":null,"abstract":"<div><div>This study investigates the influence of carbon content on the microstructure and tribological properties of FeCrMn<sub>1.5</sub>AlCuC<sub><em>x</em></sub> (<em>x</em> = 0, 0.05, 0.1, 0.15, 0.2, 0.25) high-entropy alloys. The results show that the phase structure of the alloy comprises BCC, B2, and L2<sub>1</sub> phases, with a typical dendritic microstructure. With the increase in carbon content, the critical carbon content for carbide precipitation in the alloy ranges from 0.10 to 0.15. Nanometric carbides of C (Cr, Mn, and Fe) have appeared in the interdendritic structure of the alloy. When <em>x</em> = 0.2, the alloy exhibits excellent friction performance, with a hardness of 576 HV and a wear rate of 1.6 × 10<sup>−6</sup> mm<sup>3</sup> N<sup>−1</sup> m<sup>−1</sup>. Compared with the carbon-free alloy, the alloy with <em>x</em> = 0.2 exhibits a 40.97 % increase in hardness and a 27.59 % decrease in wear rate. When the size and volume fraction of the nano-precipitates are 151.43 nm and 18.6 %, respectively, the alloy's properties are most effectively enhanced by carbon-driven optimization.</div></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"188 ","pages":"Article 109029"},"PeriodicalIF":4.8000,"publicationDate":"2025-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of carbon content on the microstructure and tribological properties of FeCrMn1.5AlCuC high-entropy alloys\",\"authors\":\"Kai Ma , Li Feng , Yanchun Zhao , Jianjun Liu\",\"doi\":\"10.1016/j.intermet.2025.109029\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This study investigates the influence of carbon content on the microstructure and tribological properties of FeCrMn<sub>1.5</sub>AlCuC<sub><em>x</em></sub> (<em>x</em> = 0, 0.05, 0.1, 0.15, 0.2, 0.25) high-entropy alloys. The results show that the phase structure of the alloy comprises BCC, B2, and L2<sub>1</sub> phases, with a typical dendritic microstructure. With the increase in carbon content, the critical carbon content for carbide precipitation in the alloy ranges from 0.10 to 0.15. Nanometric carbides of C (Cr, Mn, and Fe) have appeared in the interdendritic structure of the alloy. When <em>x</em> = 0.2, the alloy exhibits excellent friction performance, with a hardness of 576 HV and a wear rate of 1.6 × 10<sup>−6</sup> mm<sup>3</sup> N<sup>−1</sup> m<sup>−1</sup>. Compared with the carbon-free alloy, the alloy with <em>x</em> = 0.2 exhibits a 40.97 % increase in hardness and a 27.59 % decrease in wear rate. When the size and volume fraction of the nano-precipitates are 151.43 nm and 18.6 %, respectively, the alloy's properties are most effectively enhanced by carbon-driven optimization.</div></div>\",\"PeriodicalId\":331,\"journal\":{\"name\":\"Intermetallics\",\"volume\":\"188 \",\"pages\":\"Article 109029\"},\"PeriodicalIF\":4.8000,\"publicationDate\":\"2025-10-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Intermetallics\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0966979525003942\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Intermetallics","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0966979525003942","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Effect of carbon content on the microstructure and tribological properties of FeCrMn1.5AlCuC high-entropy alloys
This study investigates the influence of carbon content on the microstructure and tribological properties of FeCrMn1.5AlCuCx (x = 0, 0.05, 0.1, 0.15, 0.2, 0.25) high-entropy alloys. The results show that the phase structure of the alloy comprises BCC, B2, and L21 phases, with a typical dendritic microstructure. With the increase in carbon content, the critical carbon content for carbide precipitation in the alloy ranges from 0.10 to 0.15. Nanometric carbides of C (Cr, Mn, and Fe) have appeared in the interdendritic structure of the alloy. When x = 0.2, the alloy exhibits excellent friction performance, with a hardness of 576 HV and a wear rate of 1.6 × 10−6 mm3 N−1 m−1. Compared with the carbon-free alloy, the alloy with x = 0.2 exhibits a 40.97 % increase in hardness and a 27.59 % decrease in wear rate. When the size and volume fraction of the nano-precipitates are 151.43 nm and 18.6 %, respectively, the alloy's properties are most effectively enhanced by carbon-driven optimization.
期刊介绍:
This journal is a platform for publishing innovative research and overviews for advancing our understanding of the structure, property, and functionality of complex metallic alloys, including intermetallics, metallic glasses, and high entropy alloys.
The journal reports the science and engineering of metallic materials in the following aspects:
Theories and experiments which address the relationship between property and structure in all length scales.
Physical modeling and numerical simulations which provide a comprehensive understanding of experimental observations.
Stimulated methodologies to characterize the structure and chemistry of materials that correlate the properties.
Technological applications resulting from the understanding of property-structure relationship in materials.
Novel and cutting-edge results warranting rapid communication.
The journal also publishes special issues on selected topics and overviews by invitation only.