{"title":"无需热处理即可实现氢化物分解","authors":"Kyung-Shik Kim, Cemal Cem Tasan","doi":"10.1016/j.scriptamat.2025.117054","DOIUrl":null,"url":null,"abstract":"<div><div>For hydrogen embrittlement resistance or, potentially, for hydrogen storage, controlling hydrides is the key in HCP metals. Conventional approach for hydride decomposition relies on high-temperature thermal processes that may compromise material integrity. We present here an electrochemical process which can decompose hydrides and extract hydrogen at room temperature via surface-driven reactions. Using Ti-6Al-4V alloy as a model system, this study demonstrates that this method effectively removes hydrides without degrading the microstructure or mechanical properties, with tensile properties fully recovered to the as received state. Furthermore, no hydride reformation was observed after treatment, confirming efficient hydrogen removal. Compared to thermal decomposition, this electrochemical process offers distinct advantages, including mild operating conditions, scalable design, on-demand control via applied voltage, and compatibility with renewable energy sources. These features extend its potential beyond hydrogen embrittlement mitigation, enabling integration into distributed hydrogen storage and energy systems.</div></div>","PeriodicalId":423,"journal":{"name":"Scripta Materialia","volume":"272 ","pages":"Article 117054"},"PeriodicalIF":5.6000,"publicationDate":"2025-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Enabling hydride decomposition without heat treatments\",\"authors\":\"Kyung-Shik Kim, Cemal Cem Tasan\",\"doi\":\"10.1016/j.scriptamat.2025.117054\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>For hydrogen embrittlement resistance or, potentially, for hydrogen storage, controlling hydrides is the key in HCP metals. Conventional approach for hydride decomposition relies on high-temperature thermal processes that may compromise material integrity. We present here an electrochemical process which can decompose hydrides and extract hydrogen at room temperature via surface-driven reactions. Using Ti-6Al-4V alloy as a model system, this study demonstrates that this method effectively removes hydrides without degrading the microstructure or mechanical properties, with tensile properties fully recovered to the as received state. Furthermore, no hydride reformation was observed after treatment, confirming efficient hydrogen removal. Compared to thermal decomposition, this electrochemical process offers distinct advantages, including mild operating conditions, scalable design, on-demand control via applied voltage, and compatibility with renewable energy sources. These features extend its potential beyond hydrogen embrittlement mitigation, enabling integration into distributed hydrogen storage and energy systems.</div></div>\",\"PeriodicalId\":423,\"journal\":{\"name\":\"Scripta Materialia\",\"volume\":\"272 \",\"pages\":\"Article 117054\"},\"PeriodicalIF\":5.6000,\"publicationDate\":\"2025-10-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Scripta Materialia\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1359646225005159\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Scripta Materialia","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1359646225005159","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Enabling hydride decomposition without heat treatments
For hydrogen embrittlement resistance or, potentially, for hydrogen storage, controlling hydrides is the key in HCP metals. Conventional approach for hydride decomposition relies on high-temperature thermal processes that may compromise material integrity. We present here an electrochemical process which can decompose hydrides and extract hydrogen at room temperature via surface-driven reactions. Using Ti-6Al-4V alloy as a model system, this study demonstrates that this method effectively removes hydrides without degrading the microstructure or mechanical properties, with tensile properties fully recovered to the as received state. Furthermore, no hydride reformation was observed after treatment, confirming efficient hydrogen removal. Compared to thermal decomposition, this electrochemical process offers distinct advantages, including mild operating conditions, scalable design, on-demand control via applied voltage, and compatibility with renewable energy sources. These features extend its potential beyond hydrogen embrittlement mitigation, enabling integration into distributed hydrogen storage and energy systems.
期刊介绍:
Scripta Materialia is a LETTERS journal of Acta Materialia, providing a forum for the rapid publication of short communications on the relationship between the structure and the properties of inorganic materials. The emphasis is on originality rather than incremental research. Short reports on the development of materials with novel or substantially improved properties are also welcomed. Emphasis is on either the functional or mechanical behavior of metals, ceramics and semiconductors at all length scales.