深入研究有机超碱四十年：从设计到应用

IF 4.8 3区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Journal of Computational Chemistry Pub Date : 2025-10-18 DOI:10.1002/jcc.70250

Rabindranath Lo, Bishwajit Ganguly

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引用次数: 0

摘要

本文综述了各种中性有机超碱的设计和应用，这是一类相对较新的、被广泛采用的Brønsted碱。这些超级碱与传统的无机碱具有互补的性质，在现代合成方法中有越来越多的商业应用。综述了近年来在有机超碱的计算设计、合成和催化行为方面的研究进展。这篇文章将鼓励新型、高效和选择性催化剂的发展，使无金属条件下的高效化学转化成为可能。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

A Dive Into Forty Years of Research on Organic Superbases: From Design to Applications

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A Dive Into Forty Years of Research on Organic Superbases: From Design to Applications

This review highlights the design and applications of various types of neutral organic superbases, a relatively new and widely adopted class of Brønsted bases. These superbases offer complementary properties to conventional inorganic bases and have found increasing commercial application in modern synthetic methodologies. The recent advances in the computational design, synthesis, and catalytic behavior of organic superbases have been summarized. This article would embolden the development of novel, highly effective, and selective catalysts that enable efficient chemical transformations under metal-free conditions.

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来源期刊

Journal of Computational Chemistry 化学-化学综合

CiteScore

6.60

自引率

3.30%

发文量

247

审稿时长

1.7 months

期刊介绍： This distinguished journal publishes articles concerned with all aspects of computational chemistry: analytical, biological, inorganic, organic, physical, and materials. The Journal of Computational Chemistry presents original research, contemporary developments in theory and methodology, and state-of-the-art applications. Computational areas that are featured in the journal include ab initio and semiempirical quantum mechanics, density functional theory, molecular mechanics, molecular dynamics, statistical mechanics, cheminformatics, biomolecular structure prediction, molecular design, and bioinformatics.