{"title":"向列性和结构应变:铁基超导体的紧密连接。","authors":"Alberto Martinelli","doi":"10.1107/S1600576725007253","DOIUrl":null,"url":null,"abstract":"<p><p>In the present work, the role of microstrain developing in the temperature range above the structural transition in Fe-based superconductors is analysed in depth. Reviewing the results obtained from different compositions, a similar behaviour emerges in all cases. In particular, using an accurate diffraction line broadening analysis it is demonstrated that the tetragonal-to-orthorhombic structural transition occurring on cooling is anticipated by a symmetry breaking developing on the local scale in the tetragonal plane. The increase in microstrain with decreasing temperature in the stability field of the tetragonal phase qualitatively mirrors the development of anisotropy measured in some physical properties, a behaviour ascribed to nematicity. These results demonstrate the tight and delicate interplay correlating structural features on the local scale with transport and magnetic properties.</p>","PeriodicalId":14950,"journal":{"name":"Journal of Applied Crystallography","volume":"58 Pt 5","pages":"1789-1796"},"PeriodicalIF":2.8000,"publicationDate":"2025-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12502875/pdf/","citationCount":"0","resultStr":"{\"title\":\"Nematicity and structural strain: a tight connection in Fe-based superconductors.\",\"authors\":\"Alberto Martinelli\",\"doi\":\"10.1107/S1600576725007253\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>In the present work, the role of microstrain developing in the temperature range above the structural transition in Fe-based superconductors is analysed in depth. Reviewing the results obtained from different compositions, a similar behaviour emerges in all cases. In particular, using an accurate diffraction line broadening analysis it is demonstrated that the tetragonal-to-orthorhombic structural transition occurring on cooling is anticipated by a symmetry breaking developing on the local scale in the tetragonal plane. The increase in microstrain with decreasing temperature in the stability field of the tetragonal phase qualitatively mirrors the development of anisotropy measured in some physical properties, a behaviour ascribed to nematicity. These results demonstrate the tight and delicate interplay correlating structural features on the local scale with transport and magnetic properties.</p>\",\"PeriodicalId\":14950,\"journal\":{\"name\":\"Journal of Applied Crystallography\",\"volume\":\"58 Pt 5\",\"pages\":\"1789-1796\"},\"PeriodicalIF\":2.8000,\"publicationDate\":\"2025-09-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12502875/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Applied Crystallography\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1107/S1600576725007253\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2025/10/1 0:00:00\",\"PubModel\":\"eCollection\",\"JCR\":\"Q1\",\"JCRName\":\"Biochemistry, Genetics and Molecular Biology\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Applied Crystallography","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1107/S1600576725007253","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/10/1 0:00:00","PubModel":"eCollection","JCR":"Q1","JCRName":"Biochemistry, Genetics and Molecular Biology","Score":null,"Total":0}
Nematicity and structural strain: a tight connection in Fe-based superconductors.
In the present work, the role of microstrain developing in the temperature range above the structural transition in Fe-based superconductors is analysed in depth. Reviewing the results obtained from different compositions, a similar behaviour emerges in all cases. In particular, using an accurate diffraction line broadening analysis it is demonstrated that the tetragonal-to-orthorhombic structural transition occurring on cooling is anticipated by a symmetry breaking developing on the local scale in the tetragonal plane. The increase in microstrain with decreasing temperature in the stability field of the tetragonal phase qualitatively mirrors the development of anisotropy measured in some physical properties, a behaviour ascribed to nematicity. These results demonstrate the tight and delicate interplay correlating structural features on the local scale with transport and magnetic properties.
期刊介绍:
Many research topics in condensed matter research, materials science and the life sciences make use of crystallographic methods to study crystalline and non-crystalline matter with neutrons, X-rays and electrons. Articles published in the Journal of Applied Crystallography focus on these methods and their use in identifying structural and diffusion-controlled phase transformations, structure-property relationships, structural changes of defects, interfaces and surfaces, etc. Developments of instrumentation and crystallographic apparatus, theory and interpretation, numerical analysis and other related subjects are also covered. The journal is the primary place where crystallographic computer program information is published.