向列性和结构应变:铁基超导体的紧密连接。

IF 2.8 3区 材料科学 Q1 Biochemistry, Genetics and Molecular Biology
Journal of Applied Crystallography Pub Date : 2025-09-18 eCollection Date: 2025-10-01 DOI:10.1107/S1600576725007253
Alberto Martinelli
{"title":"向列性和结构应变:铁基超导体的紧密连接。","authors":"Alberto Martinelli","doi":"10.1107/S1600576725007253","DOIUrl":null,"url":null,"abstract":"<p><p>In the present work, the role of microstrain developing in the temperature range above the structural transition in Fe-based superconductors is analysed in depth. Reviewing the results obtained from different compositions, a similar behaviour emerges in all cases. In particular, using an accurate diffraction line broadening analysis it is demonstrated that the tetragonal-to-orthorhombic structural transition occurring on cooling is anticipated by a symmetry breaking developing on the local scale in the tetragonal plane. The increase in microstrain with decreasing temperature in the stability field of the tetragonal phase qualitatively mirrors the development of anisotropy measured in some physical properties, a behaviour ascribed to nematicity. These results demonstrate the tight and delicate interplay correlating structural features on the local scale with transport and magnetic properties.</p>","PeriodicalId":14950,"journal":{"name":"Journal of Applied Crystallography","volume":"58 Pt 5","pages":"1789-1796"},"PeriodicalIF":2.8000,"publicationDate":"2025-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12502875/pdf/","citationCount":"0","resultStr":"{\"title\":\"Nematicity and structural strain: a tight connection in Fe-based superconductors.\",\"authors\":\"Alberto Martinelli\",\"doi\":\"10.1107/S1600576725007253\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>In the present work, the role of microstrain developing in the temperature range above the structural transition in Fe-based superconductors is analysed in depth. Reviewing the results obtained from different compositions, a similar behaviour emerges in all cases. In particular, using an accurate diffraction line broadening analysis it is demonstrated that the tetragonal-to-orthorhombic structural transition occurring on cooling is anticipated by a symmetry breaking developing on the local scale in the tetragonal plane. The increase in microstrain with decreasing temperature in the stability field of the tetragonal phase qualitatively mirrors the development of anisotropy measured in some physical properties, a behaviour ascribed to nematicity. These results demonstrate the tight and delicate interplay correlating structural features on the local scale with transport and magnetic properties.</p>\",\"PeriodicalId\":14950,\"journal\":{\"name\":\"Journal of Applied Crystallography\",\"volume\":\"58 Pt 5\",\"pages\":\"1789-1796\"},\"PeriodicalIF\":2.8000,\"publicationDate\":\"2025-09-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12502875/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Applied Crystallography\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1107/S1600576725007253\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2025/10/1 0:00:00\",\"PubModel\":\"eCollection\",\"JCR\":\"Q1\",\"JCRName\":\"Biochemistry, Genetics and Molecular Biology\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Applied Crystallography","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1107/S1600576725007253","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/10/1 0:00:00","PubModel":"eCollection","JCR":"Q1","JCRName":"Biochemistry, Genetics and Molecular Biology","Score":null,"Total":0}
引用次数: 0

摘要

本文深入分析了微应变在铁基超导体结构转变以上温度范围内的作用。回顾从不同成分中获得的结果,在所有情况下都出现了类似的行为。特别地,利用精确的衍射线展宽分析表明,四边形平面局部尺度上发生的对称破缺预示了冷却时四边形向正交结构的转变。在四方相稳定场中,微应变随温度降低而增加,定性地反映了在某些物理性质中测量到的各向异性的发展,这种行为归因于向列性。这些结果表明,在局部尺度上,结构特征与输运和磁性之间存在紧密而微妙的相互作用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Nematicity and structural strain: a tight connection in Fe-based superconductors.

In the present work, the role of microstrain developing in the temperature range above the structural transition in Fe-based superconductors is analysed in depth. Reviewing the results obtained from different compositions, a similar behaviour emerges in all cases. In particular, using an accurate diffraction line broadening analysis it is demonstrated that the tetragonal-to-orthorhombic structural transition occurring on cooling is anticipated by a symmetry breaking developing on the local scale in the tetragonal plane. The increase in microstrain with decreasing temperature in the stability field of the tetragonal phase qualitatively mirrors the development of anisotropy measured in some physical properties, a behaviour ascribed to nematicity. These results demonstrate the tight and delicate interplay correlating structural features on the local scale with transport and magnetic properties.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
10.00
自引率
3.30%
发文量
178
审稿时长
4.7 months
期刊介绍: Many research topics in condensed matter research, materials science and the life sciences make use of crystallographic methods to study crystalline and non-crystalline matter with neutrons, X-rays and electrons. Articles published in the Journal of Applied Crystallography focus on these methods and their use in identifying structural and diffusion-controlled phase transformations, structure-property relationships, structural changes of defects, interfaces and surfaces, etc. Developments of instrumentation and crystallographic apparatus, theory and interpretation, numerical analysis and other related subjects are also covered. The journal is the primary place where crystallographic computer program information is published.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信