{"title":"(2-Amino-ethan-1-aminium -κN 2) tri-chlorido-zinc (II)。","authors":"Aboubacar Diop, Daouda Ndoye, Paul Tinnemans, Ennio Zangrando, Cheikh Abdoul Khadir Diop","doi":"10.1107/S2414314625007710","DOIUrl":null,"url":null,"abstract":"<p><p>The mononuclear zwitterionic Zn<sup>II</sup> complex, [ZnCl<sub>3</sub>(C<sub>2</sub>H<sub>9</sub>N<sub>2</sub>)], contains a monodentate 2-ammonio-ethyl-amine moiety and three chloride anions coordinating to the central zinc atom in form of a distorted tetra-hedron. The molecular packing shows amine and ammonium groups inter-acting through hydrogen-bonding inter-actions with chlorine atoms of symmetry-related complexes to form a supra-molecular framework structure.</p>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 Pt 9","pages":"x250771"},"PeriodicalIF":0.0000,"publicationDate":"2025-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12498028/pdf/","citationCount":"0","resultStr":"{\"title\":\"(2-Amino-ethan-1-aminium-κ<i>N</i> <sup>2</sup>)tri-chlorido-zinc(II).\",\"authors\":\"Aboubacar Diop, Daouda Ndoye, Paul Tinnemans, Ennio Zangrando, Cheikh Abdoul Khadir Diop\",\"doi\":\"10.1107/S2414314625007710\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>The mononuclear zwitterionic Zn<sup>II</sup> complex, [ZnCl<sub>3</sub>(C<sub>2</sub>H<sub>9</sub>N<sub>2</sub>)], contains a monodentate 2-ammonio-ethyl-amine moiety and three chloride anions coordinating to the central zinc atom in form of a distorted tetra-hedron. The molecular packing shows amine and ammonium groups inter-acting through hydrogen-bonding inter-actions with chlorine atoms of symmetry-related complexes to form a supra-molecular framework structure.</p>\",\"PeriodicalId\":94324,\"journal\":{\"name\":\"IUCrData\",\"volume\":\"10 Pt 9\",\"pages\":\"x250771\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2025-09-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12498028/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IUCrData\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1107/S2414314625007710\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2025/9/1 0:00:00\",\"PubModel\":\"eCollection\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1107/S2414314625007710","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/9/1 0:00:00","PubModel":"eCollection","JCR":"","JCRName":"","Score":null,"Total":0}
The mononuclear zwitterionic ZnII complex, [ZnCl3(C2H9N2)], contains a monodentate 2-ammonio-ethyl-amine moiety and three chloride anions coordinating to the central zinc atom in form of a distorted tetra-hedron. The molecular packing shows amine and ammonium groups inter-acting through hydrogen-bonding inter-actions with chlorine atoms of symmetry-related complexes to form a supra-molecular framework structure.
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