Frederick P Malan, Kariska Potgieter, Reinout Meijboom
{"title":"catena-Poly[[二-三- (4-meth-oxy-phen-yl)磷化氢-κ[P]银(I)] -μ-thio-cyanato -κ2 N: S]。","authors":"Frederick P Malan, Kariska Potgieter, Reinout Meijboom","doi":"10.1107/S2414314625008065","DOIUrl":null,"url":null,"abstract":"<p><p>The coordination polymer, [Ag(NCS)(C<sub>21</sub>H<sub>21</sub>O<sub>3</sub>P)<sub>2</sub>] <sub><i>n</i></sub> or {[Ag(P(4-OMePh)<sub>3</sub>)<sub>2</sub>]-μ-NCS} <sub><i>n</i></sub> , features μ-thio-cyanato ligands bridging between neighbouring silver(I) atoms, generating chains along the <i>b</i>-axis direction. Each Ag<sup>I</sup> atom is four-coordinate, with two phospho-rus donors from two distinct tris-(<i>p</i>-meth-oxy-phen-yl)phosphine ligands, and two atoms from the thio-cyanato ligands in severely distorted tetra-hedral shape. The Ag-P [2.4331 (6) and 2.4625 (5) Å], Ag-N [2.339 (2) Å] and Ag-S [2.6760 (6) Å] bond lengths all appear within the expected ranges, with corresponding P-Ag-P and S-Ag-N angles of 129.610 (19) and 86.75 (6)°. In the crystal, the polymeric chains pack into layers parallel to (001) separated by the aryl groups of the phosphine ligands.</p>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 Pt 9","pages":"x250806"},"PeriodicalIF":0.0000,"publicationDate":"2025-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12498030/pdf/","citationCount":"0","resultStr":"{\"title\":\"<i>catena</i>-Poly[[bis-[tris-(4-meth-oxy-phen-yl)phosphine-κ<i>P</i>]silver(I)]-μ-thio-cyanato-κ<sup>2</sup> <i>N</i>:<i>S</i>].\",\"authors\":\"Frederick P Malan, Kariska Potgieter, Reinout Meijboom\",\"doi\":\"10.1107/S2414314625008065\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>The coordination polymer, [Ag(NCS)(C<sub>21</sub>H<sub>21</sub>O<sub>3</sub>P)<sub>2</sub>] <sub><i>n</i></sub> or {[Ag(P(4-OMePh)<sub>3</sub>)<sub>2</sub>]-μ-NCS} <sub><i>n</i></sub> , features μ-thio-cyanato ligands bridging between neighbouring silver(I) atoms, generating chains along the <i>b</i>-axis direction. Each Ag<sup>I</sup> atom is four-coordinate, with two phospho-rus donors from two distinct tris-(<i>p</i>-meth-oxy-phen-yl)phosphine ligands, and two atoms from the thio-cyanato ligands in severely distorted tetra-hedral shape. The Ag-P [2.4331 (6) and 2.4625 (5) Å], Ag-N [2.339 (2) Å] and Ag-S [2.6760 (6) Å] bond lengths all appear within the expected ranges, with corresponding P-Ag-P and S-Ag-N angles of 129.610 (19) and 86.75 (6)°. In the crystal, the polymeric chains pack into layers parallel to (001) separated by the aryl groups of the phosphine ligands.</p>\",\"PeriodicalId\":94324,\"journal\":{\"name\":\"IUCrData\",\"volume\":\"10 Pt 9\",\"pages\":\"x250806\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2025-09-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12498030/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IUCrData\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1107/S2414314625008065\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2025/9/1 0:00:00\",\"PubModel\":\"eCollection\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1107/S2414314625008065","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/9/1 0:00:00","PubModel":"eCollection","JCR":"","JCRName":"","Score":null,"Total":0}
The coordination polymer, [Ag(NCS)(C21H21O3P)2] n or {[Ag(P(4-OMePh)3)2]-μ-NCS} n , features μ-thio-cyanato ligands bridging between neighbouring silver(I) atoms, generating chains along the b-axis direction. Each AgI atom is four-coordinate, with two phospho-rus donors from two distinct tris-(p-meth-oxy-phen-yl)phosphine ligands, and two atoms from the thio-cyanato ligands in severely distorted tetra-hedral shape. The Ag-P [2.4331 (6) and 2.4625 (5) Å], Ag-N [2.339 (2) Å] and Ag-S [2.6760 (6) Å] bond lengths all appear within the expected ranges, with corresponding P-Ag-P and S-Ag-N angles of 129.610 (19) and 86.75 (6)°. In the crystal, the polymeric chains pack into layers parallel to (001) separated by the aryl groups of the phosphine ligands.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
