{"title":"离子胶粘剂:设计策略、性能机制和应用","authors":"Heming Zhang, Yanan Ma, Jiaxi Fu, Shicong Fan, Xu Ou, Yingjie Zhou, Feng Yan","doi":"10.1021/acs.macromol.5c01705","DOIUrl":null,"url":null,"abstract":"Ionic adhesives, as a class of smart materials, have garnered considerable scientific interest owing to their distinct physicochemical properties and multifunctional characteristics. This review provides a systematic examination of the design principles, bonding mechanisms, and structure–property relationships governing ion-based adhesive systems. By leveraging dynamic ionic interactions and tailored polymer architectures, these materials exhibit exceptional properties, including tunable adhesion strength, environmental responsiveness, and self-healing capabilities. Their inherent reversibility and adaptability to diverse substrates enable a broad spectrum of applications in flexible electronics, biomedical engineering, and wearable devices. This review also summarizes the current research landscape of ionic adhesives, delineating challenges, and future prospects for their continued development. Ultimately, this work aims to provide theoretical guidance for creating high-performance ionic adhesives for interdisciplinary applications, thereby boosting further advancements in this rapidly evolving field.","PeriodicalId":51,"journal":{"name":"Macromolecules","volume":"56 1","pages":""},"PeriodicalIF":5.2000,"publicationDate":"2025-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Ionic Adhesives: Design Strategies, Performance Mechanisms, and Applications\",\"authors\":\"Heming Zhang, Yanan Ma, Jiaxi Fu, Shicong Fan, Xu Ou, Yingjie Zhou, Feng Yan\",\"doi\":\"10.1021/acs.macromol.5c01705\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Ionic adhesives, as a class of smart materials, have garnered considerable scientific interest owing to their distinct physicochemical properties and multifunctional characteristics. This review provides a systematic examination of the design principles, bonding mechanisms, and structure–property relationships governing ion-based adhesive systems. By leveraging dynamic ionic interactions and tailored polymer architectures, these materials exhibit exceptional properties, including tunable adhesion strength, environmental responsiveness, and self-healing capabilities. Their inherent reversibility and adaptability to diverse substrates enable a broad spectrum of applications in flexible electronics, biomedical engineering, and wearable devices. This review also summarizes the current research landscape of ionic adhesives, delineating challenges, and future prospects for their continued development. Ultimately, this work aims to provide theoretical guidance for creating high-performance ionic adhesives for interdisciplinary applications, thereby boosting further advancements in this rapidly evolving field.\",\"PeriodicalId\":51,\"journal\":{\"name\":\"Macromolecules\",\"volume\":\"56 1\",\"pages\":\"\"},\"PeriodicalIF\":5.2000,\"publicationDate\":\"2025-10-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Macromolecules\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1021/acs.macromol.5c01705\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Macromolecules","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acs.macromol.5c01705","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Ionic Adhesives: Design Strategies, Performance Mechanisms, and Applications
Ionic adhesives, as a class of smart materials, have garnered considerable scientific interest owing to their distinct physicochemical properties and multifunctional characteristics. This review provides a systematic examination of the design principles, bonding mechanisms, and structure–property relationships governing ion-based adhesive systems. By leveraging dynamic ionic interactions and tailored polymer architectures, these materials exhibit exceptional properties, including tunable adhesion strength, environmental responsiveness, and self-healing capabilities. Their inherent reversibility and adaptability to diverse substrates enable a broad spectrum of applications in flexible electronics, biomedical engineering, and wearable devices. This review also summarizes the current research landscape of ionic adhesives, delineating challenges, and future prospects for their continued development. Ultimately, this work aims to provide theoretical guidance for creating high-performance ionic adhesives for interdisciplinary applications, thereby boosting further advancements in this rapidly evolving field.
期刊介绍:
Macromolecules publishes original, fundamental, and impactful research on all aspects of polymer science. Topics of interest include synthesis (e.g., controlled polymerizations, polymerization catalysis, post polymerization modification, new monomer structures and polymer architectures, and polymerization mechanisms/kinetics analysis); phase behavior, thermodynamics, dynamic, and ordering/disordering phenomena (e.g., self-assembly, gelation, crystallization, solution/melt/solid-state characteristics); structure and properties (e.g., mechanical and rheological properties, surface/interfacial characteristics, electronic and transport properties); new state of the art characterization (e.g., spectroscopy, scattering, microscopy, rheology), simulation (e.g., Monte Carlo, molecular dynamics, multi-scale/coarse-grained modeling), and theoretical methods. Renewable/sustainable polymers, polymer networks, responsive polymers, electro-, magneto- and opto-active macromolecules, inorganic polymers, charge-transporting polymers (ion-containing, semiconducting, and conducting), nanostructured polymers, and polymer composites are also of interest. Typical papers published in Macromolecules showcase important and innovative concepts, experimental methods/observations, and theoretical/computational approaches that demonstrate a fundamental advance in the understanding of polymers.