Sergey V. Bulyarskiy, Georgy G. Gusarov, Daria A. Koiva
{"title":"氨等离子体退火过程中氧化钛的掺杂","authors":"Sergey V. Bulyarskiy, Georgy G. Gusarov, Daria A. Koiva","doi":"10.1111/jace.70142","DOIUrl":null,"url":null,"abstract":"<p>This paper studies the doping of titanium oxide films in ammonia plasma. It is shown that gas discharge alone is not enough for doping. It is necessary to increase the substrate temperature to at least 550°C, which is associated with the diffusion of ammonia into the film during plasma processing. Increasing the gas discharge power increases the plasma temperature and increases the pyrolysis rate. The nitrogen concentration and the probability of doping increase near the substrate surface. The amount of nitrogen increases, which penetrates into titanium oxide.</p>","PeriodicalId":200,"journal":{"name":"Journal of the American Ceramic Society","volume":"108 12","pages":""},"PeriodicalIF":3.8000,"publicationDate":"2025-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Doping of titanium oxide during annealing in ammonia plasma\",\"authors\":\"Sergey V. Bulyarskiy, Georgy G. Gusarov, Daria A. Koiva\",\"doi\":\"10.1111/jace.70142\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>This paper studies the doping of titanium oxide films in ammonia plasma. It is shown that gas discharge alone is not enough for doping. It is necessary to increase the substrate temperature to at least 550°C, which is associated with the diffusion of ammonia into the film during plasma processing. Increasing the gas discharge power increases the plasma temperature and increases the pyrolysis rate. The nitrogen concentration and the probability of doping increase near the substrate surface. The amount of nitrogen increases, which penetrates into titanium oxide.</p>\",\"PeriodicalId\":200,\"journal\":{\"name\":\"Journal of the American Ceramic Society\",\"volume\":\"108 12\",\"pages\":\"\"},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2025-07-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the American Ceramic Society\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://ceramics.onlinelibrary.wiley.com/doi/10.1111/jace.70142\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the American Ceramic Society","FirstCategoryId":"88","ListUrlMain":"https://ceramics.onlinelibrary.wiley.com/doi/10.1111/jace.70142","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Doping of titanium oxide during annealing in ammonia plasma
This paper studies the doping of titanium oxide films in ammonia plasma. It is shown that gas discharge alone is not enough for doping. It is necessary to increase the substrate temperature to at least 550°C, which is associated with the diffusion of ammonia into the film during plasma processing. Increasing the gas discharge power increases the plasma temperature and increases the pyrolysis rate. The nitrogen concentration and the probability of doping increase near the substrate surface. The amount of nitrogen increases, which penetrates into titanium oxide.
期刊介绍:
The Journal of the American Ceramic Society contains records of original research that provide insight into or describe the science of ceramic and glass materials and composites based on ceramics and glasses. These papers include reports on discovery, characterization, and analysis of new inorganic, non-metallic materials; synthesis methods; phase relationships; processing approaches; microstructure-property relationships; and functionalities. Of great interest are works that support understanding founded on fundamental principles using experimental, theoretical, or computational methods or combinations of those approaches. All the published papers must be of enduring value and relevant to the science of ceramics and glasses or composites based on those materials.
Papers on fundamental ceramic and glass science are welcome including those in the following areas:
Enabling materials for grand challenges[...]
Materials design, selection, synthesis and processing methods[...]
Characterization of compositions, structures, defects, and properties along with new methods [...]
Mechanisms, Theory, Modeling, and Simulation[...]
JACerS accepts submissions of full-length Articles reporting original research, in-depth Feature Articles, Reviews of the state-of-the-art with compelling analysis, and Rapid Communications which are short papers with sufficient novelty or impact to justify swift publication.