{"title":"硫酸溶液中KI对没药胶提取物对碳钢缓蚀的协同作用","authors":"Azzouz Ridha, Djellab Mounir, Bentrah Hamza, Chala Abdelouahed, Ben Ameur Mohamed Cherif, Kherief Slimane, Kabouia Amir Eddine, Bouzid Bouamra, Atassi Abdelmadjid","doi":"10.1134/S2070205125700248","DOIUrl":null,"url":null,"abstract":"<p>This study explores, for the first time, the synergistic effect between myrrh gum extract (MG) and iodide ions to enhance corrosion inhibition for API 5CT P110 tubing steel in 0.5 mol/L sulfuric acid. The interaction between MG and iodide ions was analyzed using potentiodynamic polarization curves, electrochemical impedance spectroscopy, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. Results show that the inhibition efficiency of 6 g/L MG at 20°C is 82%, but it significantly increases to 98% upon adding 5 mmol/L potassium iodide at 20°C. The system follows the Langmuir adsorption isotherm, involves both physisorption and chemisorption, and functions as a mixed-type inhibitor. The findings confirm that the combination of Ghars date extract and iodide ions provides substantial corrosion protection for API 5CT P110 tubing steel in sulfuric acid through a synergistic effect.</p>","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"61 2","pages":"488 - 501"},"PeriodicalIF":0.8000,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synergistic Effect of KI on Corrosion Inhibition of Carbon Steel by Myrrh Gum Extract in Sulfuric Acid Solution\",\"authors\":\"Azzouz Ridha, Djellab Mounir, Bentrah Hamza, Chala Abdelouahed, Ben Ameur Mohamed Cherif, Kherief Slimane, Kabouia Amir Eddine, Bouzid Bouamra, Atassi Abdelmadjid\",\"doi\":\"10.1134/S2070205125700248\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>This study explores, for the first time, the synergistic effect between myrrh gum extract (MG) and iodide ions to enhance corrosion inhibition for API 5CT P110 tubing steel in 0.5 mol/L sulfuric acid. The interaction between MG and iodide ions was analyzed using potentiodynamic polarization curves, electrochemical impedance spectroscopy, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. Results show that the inhibition efficiency of 6 g/L MG at 20°C is 82%, but it significantly increases to 98% upon adding 5 mmol/L potassium iodide at 20°C. The system follows the Langmuir adsorption isotherm, involves both physisorption and chemisorption, and functions as a mixed-type inhibitor. The findings confirm that the combination of Ghars date extract and iodide ions provides substantial corrosion protection for API 5CT P110 tubing steel in sulfuric acid through a synergistic effect.</p>\",\"PeriodicalId\":745,\"journal\":{\"name\":\"Protection of Metals and Physical Chemistry of Surfaces\",\"volume\":\"61 2\",\"pages\":\"488 - 501\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2025-09-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Protection of Metals and Physical Chemistry of Surfaces\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S2070205125700248\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"METALLURGY & METALLURGICAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Protection of Metals and Physical Chemistry of Surfaces","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1134/S2070205125700248","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
Synergistic Effect of KI on Corrosion Inhibition of Carbon Steel by Myrrh Gum Extract in Sulfuric Acid Solution
This study explores, for the first time, the synergistic effect between myrrh gum extract (MG) and iodide ions to enhance corrosion inhibition for API 5CT P110 tubing steel in 0.5 mol/L sulfuric acid. The interaction between MG and iodide ions was analyzed using potentiodynamic polarization curves, electrochemical impedance spectroscopy, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. Results show that the inhibition efficiency of 6 g/L MG at 20°C is 82%, but it significantly increases to 98% upon adding 5 mmol/L potassium iodide at 20°C. The system follows the Langmuir adsorption isotherm, involves both physisorption and chemisorption, and functions as a mixed-type inhibitor. The findings confirm that the combination of Ghars date extract and iodide ions provides substantial corrosion protection for API 5CT P110 tubing steel in sulfuric acid through a synergistic effect.
期刊介绍:
Protection of Metals and Physical Chemistry of Surfaces is an international peer reviewed journal that publishes articles covering all aspects of the physical chemistry of materials and interfaces in various environments. The journal covers all related problems of modern physical chemistry and materials science, including: physicochemical processes at interfaces; adsorption phenomena; complexing from molecular and supramolecular structures at the interfaces to new substances, materials and coatings; nanoscale and nanostructured materials and coatings, composed and dispersed materials; physicochemical problems of corrosion, degradation and protection; investigation methods for surface and interface systems, processes, structures, materials and coatings. No principe restrictions exist related systems, types of processes, methods of control and study. The journal welcomes conceptual, theoretical, experimental, methodological, instrumental, environmental, and all other possible studies.