用于芳香增强的粘胶纤维基纱线

IF 0.8 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING
Hongling Hao, Yi-Fan Bu, Li Jiang, Chengyu He, Zexing Zhu, Yun Wu, Dan Zhang, Jiehui Li
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引用次数: 0

摘要

粘胶纤维是一种再生纤维素材料,由于其具有可调节的亲水性、吸附能力和力学性能,在吸附方面具有潜在的应用前景。本研究系统地表征了六种不同纱线的组成、物理性能和吸附性能,并探讨了结构-性能关系。它证实了纤维的组成,并揭示了明显的亲疏水变化。机械测试表明,由于水引起的氢键破坏,在潮湿状态下强度比干燥状态降低50%。作为风味分子的一种模型,法尼醇的吸附行为是由最初通过氢键和范德华力的快速表面附着决定的,随后是通过非晶区缓慢的纤维内扩散。温度相关研究(25-45°C)证明了在高温下从多层吸附(Freundlich模型)到单层覆盖(Langmuir模型)的转变,热力学分析证实了该过程的吸热性质。吸附遵循准二级动力学,表明化学吸附为主。这些发现阐明了粘胶纤维性能的基本机制,为设计先进的纤维素基功能材料提供了科学依据。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Viscose Fiber-Based Yarns for Aroma Enhancement

Viscose Fiber-Based Yarns for Aroma Enhancement

Viscose fiber, a regenerated cellulose material, has attracted significant attention for its potential in adsorption applications due to its tunable hydrophilicity, adsorption capacity, and mechanical properties. This study systematically characterizes six different yarns’ composition, physical properties, and adsorption capabilities and investigates the structure-property relationships. It confirmed the fibers’ composition and revealed distinct hydrophilic-hydrophobic variations. Mechanical testing showed 50% strength reduction in wet states compared to dry states due to water-induced disruption of hydrogen bonding. The adsorption behaviors of farnesol, a model of flavor molecule, were governed by the initial rapid surface attachment via hydrogen bonding and van der Waals forces, followed by slower intra-fiber diffusion through the amorphous regions. Temperature-dependent studies (25–45°C) demonstrated a transition from multilayer adsorption (Freundlich model) to monolayer coverage (Langmuir model) at elevated temperatures, with thermodynamic analysis confirming the endothermic nature of the process. The adsorption follows the pseudo-second-order kinetics, indicating chemisorption-dominated adsorption. These findings elucidate the fundamental mechanisms underlying viscose fiber performance and provide a scientific basis for designing advanced cellulose-based functional materials.

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来源期刊
CiteScore
1.90
自引率
18.20%
发文量
90
审稿时长
4-8 weeks
期刊介绍: Protection of Metals and Physical Chemistry of Surfaces is an international peer reviewed journal that publishes articles covering all aspects of the physical chemistry of materials and interfaces in various environments. The journal covers all related problems of modern physical chemistry and materials science, including: physicochemical processes at interfaces; adsorption phenomena; complexing from molecular and supramolecular structures at the interfaces to new substances, materials and coatings; nanoscale and nanostructured materials and coatings, composed and dispersed materials; physicochemical problems of corrosion, degradation and protection; investigation methods for surface and interface systems, processes, structures, materials and coatings. No principe restrictions exist related systems, types of processes, methods of control and study. The journal welcomes conceptual, theoretical, experimental, methodological, instrumental, environmental, and all other possible studies.
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