Soumaya Gouadria, F. F. Alharbi, Muhammad Abdullah, Salma Aman, Tehreem Zahra, Hafiz Muhammad Tahir Farid
{"title":"钙钛矿/g-C3N4纳米杂化物作为超级电容器先进电极材料的研究进展","authors":"Soumaya Gouadria, F. F. Alharbi, Muhammad Abdullah, Salma Aman, Tehreem Zahra, Hafiz Muhammad Tahir Farid","doi":"10.1007/s12678-025-00950-w","DOIUrl":null,"url":null,"abstract":"<div><p>New energy storing technologies must be developed immediately because of the serious issues brought by global energy crisis. For supercapacitor applications, the development of effective, stable and sustainable electrode materials with high specific capacitance (C<sub>sp</sub>) is necessary. The current investigation highlights the use of CoMoO<sub>3</sub>/g-CN electrode materials to enhance supercapacitive properties. The physical and chemical properties hydrothermally developed materials were studied utilising a number of characterisation test. In 3 M KOH solution, electrochemical characteristics of produced electrode materials were observed by galvanostatic charge and discharge (GCD) analysis and cyclic voltammetry. Electrochemical results exposed that CoMoO<sub>3</sub>/g-CN nanocomposite exhibited specific capacitance of 964.93 F/g, specific energy (S<sub>E</sub>) 44.09 Wh/kg and specific power (S<sub>P</sub>) 288.15 W/kg at current density (C<sub>d</sub>) 1 A/g. Furthermore, after 3000th cycles, the material exhibits superior cyclic stability compared to the pure material and reduced charge transfer resistance of 0.13 Ω. Addition of graphitic carbon nitride (g-CN) caused high specific capacitance, quick charging discharging and stability of active electrode material, attributed to bigger surface area and excellent electrical conductivity. Moreover, N-enrich structure of g-CN caused a quick ion transport and higher specific surface area. These results demonstrated that advanced CoMoO<sub>3</sub>/g-CN can be applied to next-generation supercapacitors.</p><h3>Graphical Abstract</h3>\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":535,"journal":{"name":"Electrocatalysis","volume":"16 4","pages":"738 - 748"},"PeriodicalIF":2.8000,"publicationDate":"2025-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Facile Development of Perovskite/g-C3N4 Nanohybrid as Advance Electrode Materials for Supercapacitor\",\"authors\":\"Soumaya Gouadria, F. F. Alharbi, Muhammad Abdullah, Salma Aman, Tehreem Zahra, Hafiz Muhammad Tahir Farid\",\"doi\":\"10.1007/s12678-025-00950-w\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>New energy storing technologies must be developed immediately because of the serious issues brought by global energy crisis. For supercapacitor applications, the development of effective, stable and sustainable electrode materials with high specific capacitance (C<sub>sp</sub>) is necessary. The current investigation highlights the use of CoMoO<sub>3</sub>/g-CN electrode materials to enhance supercapacitive properties. The physical and chemical properties hydrothermally developed materials were studied utilising a number of characterisation test. In 3 M KOH solution, electrochemical characteristics of produced electrode materials were observed by galvanostatic charge and discharge (GCD) analysis and cyclic voltammetry. Electrochemical results exposed that CoMoO<sub>3</sub>/g-CN nanocomposite exhibited specific capacitance of 964.93 F/g, specific energy (S<sub>E</sub>) 44.09 Wh/kg and specific power (S<sub>P</sub>) 288.15 W/kg at current density (C<sub>d</sub>) 1 A/g. Furthermore, after 3000th cycles, the material exhibits superior cyclic stability compared to the pure material and reduced charge transfer resistance of 0.13 Ω. Addition of graphitic carbon nitride (g-CN) caused high specific capacitance, quick charging discharging and stability of active electrode material, attributed to bigger surface area and excellent electrical conductivity. Moreover, N-enrich structure of g-CN caused a quick ion transport and higher specific surface area. These results demonstrated that advanced CoMoO<sub>3</sub>/g-CN can be applied to next-generation supercapacitors.</p><h3>Graphical Abstract</h3>\\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":535,\"journal\":{\"name\":\"Electrocatalysis\",\"volume\":\"16 4\",\"pages\":\"738 - 748\"},\"PeriodicalIF\":2.8000,\"publicationDate\":\"2025-04-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Electrocatalysis\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s12678-025-00950-w\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Electrocatalysis","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s12678-025-00950-w","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
摘要
由于全球能源危机带来的严重问题,必须立即开发新的储能技术。对于超级电容器的应用,开发高效、稳定、可持续的高比电容电极材料是必要的。目前的研究重点是使用CoMoO3/g-CN电极材料来增强超级电容性能。利用一系列表征试验研究了水热开发材料的物理和化学性质。在3 M KOH溶液中,采用恒流充放电(GCD)分析和循环伏安法观察电极材料的电化学特性。电化学结果表明,在电流密度(Cd)为1 A/g时,CoMoO3/g- cn纳米复合材料的比电容为964.93 F/g,比能量为44.09 Wh/kg,比功率为288.15 W/kg。此外,经过3000次循环后,与纯材料相比,该材料表现出更好的循环稳定性,电荷转移电阻降低了0.13 Ω。石墨化碳氮化(g-CN)的加入使活性电极材料的比电容高,充放电快,稳定性好,具有较大的比表面积和优异的导电性。此外,g-CN的富n结构使其离子传输速度快,比表面积高。这些结果表明,先进的CoMoO3/g-CN可以应用于下一代超级电容器。图形抽象
Facile Development of Perovskite/g-C3N4 Nanohybrid as Advance Electrode Materials for Supercapacitor
New energy storing technologies must be developed immediately because of the serious issues brought by global energy crisis. For supercapacitor applications, the development of effective, stable and sustainable electrode materials with high specific capacitance (Csp) is necessary. The current investigation highlights the use of CoMoO3/g-CN electrode materials to enhance supercapacitive properties. The physical and chemical properties hydrothermally developed materials were studied utilising a number of characterisation test. In 3 M KOH solution, electrochemical characteristics of produced electrode materials were observed by galvanostatic charge and discharge (GCD) analysis and cyclic voltammetry. Electrochemical results exposed that CoMoO3/g-CN nanocomposite exhibited specific capacitance of 964.93 F/g, specific energy (SE) 44.09 Wh/kg and specific power (SP) 288.15 W/kg at current density (Cd) 1 A/g. Furthermore, after 3000th cycles, the material exhibits superior cyclic stability compared to the pure material and reduced charge transfer resistance of 0.13 Ω. Addition of graphitic carbon nitride (g-CN) caused high specific capacitance, quick charging discharging and stability of active electrode material, attributed to bigger surface area and excellent electrical conductivity. Moreover, N-enrich structure of g-CN caused a quick ion transport and higher specific surface area. These results demonstrated that advanced CoMoO3/g-CN can be applied to next-generation supercapacitors.
期刊介绍:
Electrocatalysis is cross-disciplinary in nature, and attracts the interest of chemists, physicists, biochemists, surface and materials scientists, and engineers. Electrocatalysis provides the unique international forum solely dedicated to the exchange of novel ideas in electrocatalysis for academic, government, and industrial researchers. Quick publication of new results, concepts, and inventions made involving Electrocatalysis stimulates scientific discoveries and breakthroughs, promotes the scientific and engineering concepts that are critical to the development of novel electrochemical technologies.
Electrocatalysis publishes original submissions in the form of letters, research papers, review articles, book reviews, and educational papers. Letters are preliminary reports that communicate new and important findings. Regular research papers are complete reports of new results, and their analysis and discussion. Review articles critically and constructively examine development in areas of electrocatalysis that are of broad interest and importance. Educational papers discuss important concepts whose understanding is vital to advances in theoretical and experimental aspects of electrochemical reactions.