原位生成高价碘化合物催化醛肟和ewg取代烯烃电化学合成异恶唑啉

IF 0.9 4区化学 Q4 CHEMISTRY, ORGANIC

Russian Journal of Organic Chemistry Pub Date : 2025-07-13 DOI:10.1134/S1070428025602213

O. V. Bityukov, A. S. Kirillov, V. A. Vil’, G. I. Nikishin, A. O. Terent’ev

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引用次数: 0

摘要

在原位生成的高价碘化合物的辅助下，我们开发了由醛肟和ewg取代的烯烃电化学合成异恶唑啉的方法。在未分裂细胞中恒流条件下，以20-48%的产率获得了广泛的具有杀真菌活性的取代异恶唑啉。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Electrochemical Synthesis of Isoxazolines from Aldoximes and EWG-Substituted Alkenes Enabling by In Situ Generated Hypervalent Iodine Compounds

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Electrochemical Synthesis of Isoxazolines from Aldoximes and EWG-Substituted Alkenes Enabling by In Situ Generated Hypervalent Iodine Compounds

We developed the electrochemical synthesis of isoxazolines from aldoximes and EWG-substituted alkenes with the assistance of the in situ generated hypervalent iodine compounds. A wide range of substituted isoxazolines possessing fungicidal activity were obtained in 20–48% yields under constant current conditions in an undivided cell.

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来源期刊

Russian Journal of Organic Chemistry 化学-有机化学

CiteScore

1.40

自引率

25.00%

发文量

139

审稿时长

3-6 weeks

期刊介绍： Russian Journal of Organic Chemistry is an international peer reviewed journal that covers all aspects of modern organic chemistry including organic synthesis, theoretical organic chemistry, structure and mechanism, and the application of organometallic compounds in organic synthesis.