M - go /(h-BN)n/M - go (M = Be, B)复合高电容金属掺杂介质电容器的实验与理论研究

IF 1.4 4区 化学 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL
M. Monajjemi, F. Mollaamin, S. Shahriari, S. Mohammadi
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引用次数: 0

摘要

虽然,减少介电绝缘的尺寸,如薄膜的厚度,会导致介电电容器的电容增加,但在量子维度上,由于隧道效应通常会共同降低极小微结构的电容,这种效应变得相反。换句话说,电容器的几何尺寸与经典静电学的预期形成鲜明对比。通过这项工作,我们预测由氧化石墨烯(GO)和六方氮化硼(h-BN)薄膜制成的介电微电容器可以生产出性能优越的电容器。特别是在氧化石墨烯中掺杂金属,如Be-GO和B-GO,可以极大地增加容量。我们的工作是基于两种方法完成的,一种是在微观尺度上实验完成的介质电容器,另一种是在理论上模拟的埃维量子理论。我们发现,在这两种方法中,金属氧化石墨烯电极与h-BN作为绝缘体的组合可以惊人地提高电容。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Experimental and Theoretical Study of metal Doped Dielectric Capacitors Composd with M–GO/(h-BN)n/M–GO(M = Be, B): A High Capacitance at Micro-Scale

Experimental and Theoretical Study of metal Doped Dielectric Capacitors Composd with M–GO/(h-BN)n/M–GO(M = Be, B): A High Capacitance at Micro-Scale

Although, reducing dimensions of dielectric insulation such as thickness of a film, cause increasing capacitance in a dielectric capacitor, but in quantum dimension this effect become inverse due to the tunneling effect often conspire to decrease the capacitance of extremely small microstructures. In other words, the geometric dimension in a capacitor is in a sharp contrast to what is expected from classical electrostatics. By this work we have predicted that a dielectric micro-capacitor made of graphene oxide (GO) and hexagonal boron nitride (h-BN) films can produce superior capacitors. Especially doped metals in the graphene oxide such as Be–GO and B–GO can increase the capacity, extremely. Our work was accomplished based on two approaches including, 1—by dielectric-capacitor that was done experimentally in micro scale and second via quantum theory in angstrom dimensions, which was simulated, theoretically. We found in both approaches a combination of metal-GO electrodes with h-BN as insulator can enhance the capacitance, amazingly.

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来源期刊
Russian Journal of Physical Chemistry B
Russian Journal of Physical Chemistry B 化学-物理:原子、分子和化学物理
CiteScore
2.20
自引率
71.40%
发文量
106
审稿时长
4-8 weeks
期刊介绍: Russian Journal of Physical Chemistry B: Focus on Physics is a journal that publishes studies in the following areas: elementary physical and chemical processes; structure of chemical compounds, reactivity, effect of external field and environment on chemical transformations; molecular dynamics and molecular organization; dynamics and kinetics of photoand radiation-induced processes; mechanism of chemical reactions in gas and condensed phases and at interfaces; chain and thermal processes of ignition, combustion and detonation in gases, two-phase and condensed systems; shock waves; new physical methods of examining chemical reactions; and biological processes in chemical physics.
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