丙烯酸酯和甲基丙烯酸酯配体八面体钼配合物的钠盐

IF 1.4 4区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Journal of Structural Chemistry Pub Date : 2025-08-05 DOI:10.1134/S0022476625070078

N. A. Vorotnikova, A. S. Berezin, N. V. Kuratieva, M. A. Shestopalov, Y. A. Vorotnikov

{"title":"丙烯酸酯和甲基丙烯酸酯配体八面体钼配合物的钠盐","authors":"N. A. Vorotnikova, A. S. Berezin, N. V. Kuratieva, M. A. Shestopalov, Y. A. Vorotnikov","doi":"10.1134/S0022476625070078","DOIUrl":null,"url":null,"abstract":"Two new molybdenum cluster complexes Na2[Mo6I8L6] (L = –CH2=CH–COO– (acrylate, Acr–) and –CH2=C(CH3)–COO– (methacrylate, MAcr–)) are prepared and studied. The complexes are prepared by solvothermal synthesis in methanol from Na2[Mo6I8(OMe)6] in the presence of small excess of the corresponding organic acid. As a result, XRD-quality single crystals of Na2[Mo6I8L6]·2MeOH are formed. The composition and purity of the phases are confirmed by the CHN elemental analysis, energy dispersion analysis, IR spectroscopy, and powder XRD. Photoluminescent properties of both complexes in the solid state and in a dimethylformamide solution are studied.","PeriodicalId":668,"journal":{"name":"Journal of Structural Chemistry","volume":"66 7","pages":"1403 - 1411"},"PeriodicalIF":1.4000,"publicationDate":"2025-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Sodium Salts of Octahedral Molybdenum Complexes with Acrylate and Methacrylate Ligands\",\"authors\":\"N. A. Vorotnikova, A. S. Berezin, N. V. Kuratieva, M. A. Shestopalov, Y. A. Vorotnikov\",\"doi\":\"10.1134/S0022476625070078\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Two new molybdenum cluster complexes Na2[Mo6I8L6] (L = –CH2=CH–COO– (acrylate, Acr–) and –CH2=C(CH3)–COO– (methacrylate, MAcr–)) are prepared and studied. The complexes are prepared by solvothermal synthesis in methanol from Na2[Mo6I8(OMe)6] in the presence of small excess of the corresponding organic acid. As a result, XRD-quality single crystals of Na2[Mo6I8L6]·2MeOH are formed. The composition and purity of the phases are confirmed by the CHN elemental analysis, energy dispersion analysis, IR spectroscopy, and powder XRD. Photoluminescent properties of both complexes in the solid state and in a dimethylformamide solution are studied.\",\"PeriodicalId\":668,\"journal\":{\"name\":\"Journal of Structural Chemistry\",\"volume\":\"66 7\",\"pages\":\"1403 - 1411\"},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2025-08-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Structural Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0022476625070078\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Structural Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0022476625070078","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}

引用次数: 0

摘要

制备了两种新型钼团簇配合物Na2[Mo6I8L6] (L = - ch2 = CH-COO -（丙烯酸酯，Acr -）和- ch2 =C（CH3) - coo -（甲基丙烯酸酯，MAcr -））。在少量过量的相应有机酸存在下，以Na2[Mo6I8(OMe)6]为原料，在甲醇中溶剂热合成了配合物。结果形成了具有xrd质量的Na2[Mo6I8L6]·2MeOH单晶。通过CHN元素分析、能量色散分析、红外光谱分析和粉末XRD分析，确定了相的组成和纯度。研究了这两种配合物在固体和二甲基甲酰胺溶液中的光致发光性能。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Sodium Salts of Octahedral Molybdenum Complexes with Acrylate and Methacrylate Ligands

查看原文本刊更多论文

Sodium Salts of Octahedral Molybdenum Complexes with Acrylate and Methacrylate Ligands

Two new molybdenum cluster complexes Na₂[Mo₆I₈L₆] (L = –CH₂=CH–COO^– (acrylate, Acr^–) and –CH₂=C(CH₃)–COO^– (methacrylate, MAcr^–)) are prepared and studied. The complexes are prepared by solvothermal synthesis in methanol from Na₂[Mo₆I₈(OMe)₆] in the presence of small excess of the corresponding organic acid. As a result, XRD-quality single crystals of Na₂[Mo₆I₈L₆]·2MeOH are formed. The composition and purity of the phases are confirmed by the CHN elemental analysis, energy dispersion analysis, IR spectroscopy, and powder XRD. Photoluminescent properties of both complexes in the solid state and in a dimethylformamide solution are studied.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Journal of Structural Chemistry 化学-无机化学与核化学

CiteScore

1.60

自引率

12.50%

发文量

142

审稿时长

8.3 months

期刊介绍： Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.