I. M. Gavrilin, I. S. Marinkin, E. V. Kovtushenko, L. S. Volkova, T. L. Kulova, A. M. Skundin
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引用次数: 0
摘要
研究了锗钴银纳米结构的合成参数对其电化学性能的影响。结果表明,Ge(IV)与Co(II)水溶液的最佳配比为GeCo(3:2),在此条件下,得到的样品在第一次循环时的库仑效率最高,达到80%,插锂容量为1190 mA h/g。将溶液温度提高到40°C,在不使用特殊有机添加剂的情况下,样品的库仑效率约为92%。
Effect of Parameters of Synthesis on the Electrochemical Properties of Ge–Co–In Nanostructures
Results are presented from investigating the effect the parameters of synthesis of Ge–Co–In nanostructures have on their electrochemical properties. It is found that the optimum ratio of aqueous complex solutions of Ge(IV) and Co(II) is GeCo (3 : 2), at which the obtained sample have the highest Coulombic efficiency of 80% at the first cycle equal and reversible capacity with respect to lithium insertion about 1190 mA h/g. Raising the temperature of the solution to 40°C yields samples that have Coulombic efficiencies of approximately 92% without using special organic additives in the electrolyte.
期刊介绍:
Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world.
Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.